Electrocatalysis of 2-Diethylaminoethanethiol at Nickel Nanoparticle-Electrodecorated Single-Walled Carbon Nanotube Platform: An Adsorption-Controlled Electrode Process

被引:18
作者
Adekunle, Abolanle S. [1 ]
Pillay, Jeseelan [1 ]
Ozoemena, Kenneth I. [1 ]
机构
[1] Univ Pretoria, Dept Chem, Mol & Nanomat Electrochem Lab, ZA-0002 Pretoria, South Africa
关键词
Nickel nanoparticles; Single-walled carbon nanotubes; Diethylaminoethanethiol; Impedance spectroscopy; Adsorption; Voltammetry;
D O I
10.1002/elan.200804355
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Electrocatalytic behavior of diethylaminoethanethiol (DEAET) at nickel nanoparticle-electrodecorated single-walled carbon nanotube (SWCNF-Ni) platform is presented. We demonstrate that the electrocatalytic response is governed by adsorption-control led kinetics and that adsorptive stripping voltammetry (AdsSV) represents a viable analytical voltammetry for the sensitive detection of this hydrolysis product of a V-type nerve agent.
引用
收藏
页码:2587 / 2591
页数:5
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