Hydrogen bond detachment in polymer complexes

被引:36
|
作者
Ma, Songmei [1 ]
Qi, Xiaocun [1 ]
Cao, Yugai [1 ]
Yang, Shuguang [1 ]
Xu, Jian [1 ,2 ]
机构
[1] Donghua Univ, Coll Mat Sci & Engn, State Key Lab Modificat Chem Fibers & Polymer Mat, Shanghai 201620, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
Hydrogen bond; Hydrogen bond breakage; Polymer complex; AQUEOUS-SOLUTION; POLY(ACRYLIC ACID); INTERMACROMOLECULAR COMPLEXES; WEAK POLYELECTROLYTE; ASSEMBLY FILM; IONIC LIQUIDS; CELLULOSE; TEMPERATURE; DISSOLUTION; MULTILAYER;
D O I
10.1016/j.polymer.2013.07.047
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The hydrogen bonded polymer complex bulk and thin film was prepared by solution mixing and layer-by-layer assembly, respectively. Poly(vinylpyrrolidone) (PVPON) and poly(ethylene oxide) (PEO) were hydrogen bonding acceptor polymers while poly(acrylic acid) (PAA) and poly(methacrylic acid) (PMAA) were hydrogen bonding donor polymers. The detachment of hydrogen bond between the chains in polymer complexes was investigated during the dissolution in alkaline solution, ionic liquid and tertiary amine N-oxide. We compared the dissolution process of the polymer complex bulk with the polymer complex thin film, and discussed the polymer chain length, chain entanglement degree and temperature effect on hydrogen bond detachment and dissolution of polymer complexes. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5382 / 5390
页数:9
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