Some recent developments in headspace gas chromatography

被引:41
作者
Zhu, JY
Chai, XS
机构
[1] US Forest Serv, USDA, Forest Prod Lab, Madison, WI 53726 USA
[2] Georgia Inst Technol, Inst Paper Sci & Technol, Atlanta, GA 30332 USA
关键词
headspace; chromatography; vapor-liquid equilibrium; solubility; kinetics; reaction conversion; phase; full evaporation; multiple headspace extraction;
D O I
10.2174/1573411052948488
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In this study, recent developments in headspace gas chromatography (HSGC) are briefly reviewed. Several novel HSGC techniques developed recently are presented in detail. These techniques were developed using the unique characteristics of the headspace sampling process implemented in commercial HSGC systems and therefore can be easily applied in laboratory and industrial practices. These techniques greatly expand the capability of traditional HSGC from simply analysis of volatile species to the measurements of nonvolatile species in solid systems and their properties in aqueous systems. The basic principles of the techniques along with specific applications are presented. These HSGC techniques are practical, accurate, and simple for both laboratory and industrial applications.
引用
收藏
页码:79 / 83
页数:5
相关论文
共 35 条
[1]  
Burrows DL, 2004, J FORENSIC SCI, V49, P394
[2]   Headspace SPME method development for the analysis of volatile polar residual solvents by GC-MS [J].
Camarasu, CC .
JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 2000, 23 (01) :197-210
[3]   Evaluation of dynamic headspace and purge-and-trap techniques for the high-resolution gas chromatography analysis of nitrous oxide in seawater [J].
Careri, M ;
Mori, G ;
Musci, M ;
Viaroli, P .
JOURNAL OF CHROMATOGRAPHY A, 1999, 848 (1-2) :327-335
[4]  
Chai XS, 2000, J PULP PAP SCI, V26, P167
[5]   Determination of residual monomer in polymer latex by full evaporation headspace gas chromatography [J].
Chai, XS ;
Hou, QX ;
Schork, FJ .
JOURNAL OF CHROMATOGRAPHY A, 2004, 1040 (02) :163-167
[6]   Carboxyl groups in wood fibers. 1. Determination of carboxyl groups by headspace gas chromatography [J].
Chai, XS ;
Hou, QX ;
Zhu, JY ;
Chen, SL ;
Wang, SF ;
Lucia, L .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2003, 42 (22) :5440-5444
[7]   Multiple headspace extraction-gas chromatographic method for the study of process kinetics [J].
Chai, XS ;
Luo, Q ;
Zhu, JY .
JOURNAL OF CHROMATOGRAPHY A, 2002, 946 (1-2) :177-183
[8]   Determination of the solubility of inorganic salts by headspace gas chromatography [J].
Chai, XS ;
Zhu, JY .
JOURNAL OF CHROMATOGRAPHY A, 2003, 996 (1-2) :157-161
[9]   Analysis of nonvolatile species in a complex matrix by headspace gas chromatography [J].
Chai, XS ;
Luo, Q ;
Zhu, JY .
JOURNAL OF CHROMATOGRAPHY A, 2001, 909 (02) :249-257
[10]   Simultaneous measurements of solute concentration and Henry's constant using multiple headspace extraction gas chromatography [J].
Chai, XS ;
Zhu, JY .
ANALYTICAL CHEMISTRY, 1998, 70 (16) :3481-3487