The crystal structure of Ca3ReO6

被引：15

作者：

Abakumov, AM

Shpanchenko, RV

Antipov, EV

Lebedev, OI

VanTendeloo, G

机构：

[1] MOSCOW MV LOMONOSOV STATE UNIV,DEPT CHEM,MOSCOW 119899,RUSSIA

[2] UNIV ANTWERP,RIJKSUNIV CTR ANTWERP,EMAT,B-2020 ANTWERP,BELGIUM

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1997年 / 131卷 / 02期

基金：

俄罗斯科学基金会;

关键词：

D O I：

10.1006/jssc.1997.7384

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex oxide Ca3ReO6 was synthesized and its crystal structure determined using X-ray powder analysis (space group P2(1)/n; a = 5.53664(5) Angstrom; b = 5.80322(5) Angstrom; c = 7.98492(7) Angstrom; beta = 90.073(1)degrees; R-I = 0.032, R-P = 0.069, R-wP = 0.095; Z = 2). The real symmetry is monoclinic due to a simultaneous tilt and rotation of the CaO6 and ReO6 octahedra. Electron diffraction and electron microscopy confirm the X-ray results, Ca3ReO6 is isostructural with A(2)RRuO(6) oxides. (C) 1997 Academic Press.

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收藏

页码：305 / 309

页数：5

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