The Au(III)-catalyzed coupling reactions between alcohols and N-heterocycles via C-H bond activation

被引：25

作者：

Jiang, Honglai ^{[1
]}

Xie, Jin ^{[1
]}

Lin, Aijun ^{[1
]}

Cheng, Yixiang ^{[1
]}

Zhu, Chengjian ^{[1
,2
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

RSC ADVANCES | 2012年 / 2卷 / 28期

基金：

中国国家自然科学基金;

关键词：

FREE-RADICAL REACTIONS; TRANSFER HYDROGENATION; CATALYSIS; OXIDATION; ACYLATION; OXYGEN;

D O I：

10.1039/c2ra22120a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel and highly efficient dehydrogenative C-C coupling between sp(3) C-H and sp(2) C-H bonds catalyzed by gold has been developed using environmentally benign tert-butyl hydroperoxide as oxidant. This new methodology provides a facile access to acylate N-heterocycles.

引用

页码：10496 / 10498

页数：3

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