Novel dihydridoruthenium(II) complexes with chelating diphosphine ligands, RuH2(CO)(diphosphine)(PPh3) (diphosphine = dppe, dppp, dppb, and dppf)

被引：0
作者：
Kawano, H
Tanaka, R
Fujikawa, T
Hiraki, K [1 ]
Onishi, M
机构：
[1] Nagasaki Univ, Fac Engn, Dept Appl Chem, Nagasaki 8528521, Japan
[2] Nagasaki Univ, Grad Sch Marine Sci & Engn, Nagasaki 8528521, Japan
来源：
CHEMISTRY LETTERS | 1999年 / 05期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Ligand exchange of [RuH2(CO)(PPh3)(3)] with some diphosphine ligands affords a series of [RuH2(CO)(diphosphine)(PPh3)] (diphosphine = dppe, dppp, dppb, and dppf). The X-ray structure analysis of [RuH2(CO)(dppp)(PPh3)] reveals its distorted octahedral structure. The diphosphine ligand complexes react with styrene to generate ruthenium(0) species, which successively proceed with the intramolecular C-H addition to give the cyclometallated aryl(hydrido)ruthenium(II) species.
引用
收藏
页码：401 / 402
页数：2
相关论文
共 50 条
[41]   REACTION BETWEEN [RE3H3(CO)12] AND THE DIPHOSPHINE LIGANDS PH2PCH2PPH2 AND (ETO)2POP(OET)2 - X-RAY CRYSTAL-STRUCTURES OF [RE2H2(CO)6(PH2PCH2PPH2)] AND [RE3H3(CO)8((ETO)2POP(OET)2)2] [J].
PREST, DW ;
MAYS, MJ ;
RAITHBY, PR ;
ORPEN, AG .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (04) :737-745
[42]   Cyclopalladated compounds with bridging and chelating diphosphine ligands.: Effect of ring size.: Crystal and molecular structure of [{Pd[4-(COH)C6H3C(H)=N(Cy)-C2,N](Cl)}2(μ-Ph2PCH2PPh2)] [J].
Ares, R ;
López-Torres, M ;
Fernández, A ;
Castro-Juiz, S ;
Suarez, A ;
Alberdi, G ;
Fernández, JJ ;
Vila, JM .
POLYHEDRON, 2002, 21 (22) :2309-2315
[43]   Bridging and chelating diphosphine ligands in Ru3(μ-H)(μ-N=CPh2)(CO)8(P-P).: X-ray diffraction structures of Ru3(μ-H)(μ-N=CPh2)(CO)8(dmpe) and Ru3(μ-H)(μ-N=CPh2)(CO)8(bpcd) [J].
Watson, WH ;
Mendez-Rojas, MA ;
Zhao, YX ;
Richmond, MG .
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2003, 33 (10) :765-774
[44]   TRIOSMIUM ALKYLIDYNE CLUSTERS CONTAINING MONOPHOSPHINE AND CHIRAL DIPHOSPHINE LIGANDS - CRYSTAL AND MOLECULAR-STRUCTURES OF [OS-3(MU-H)(2)(CO)(9)(MU(3)-CPBU(N)PH(2))] AND (R)-[OS-3(MU-H)(2)(CO)(8)(MU(3)-CPPH(2)CH(ME)CH(2)PPH(2))] [J].
WONG, WY ;
WONG, WT .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (17) :2831-2836
[45]   Mononuclear chelating diselenito complexes of platinum(II) and the crystal structure of bis-triphenylphosphine(diselenito-O, O′) platinum(II) -: Preference for hard versus soft ligands of the cis-Pt(PPh3)2 moiety? [J].
Battan, L ;
Manassero, M ;
Pasini, A .
INORGANIC CHEMISTRY COMMUNICATIONS, 2001, 4 (11) :606-609
[46]   CATIONIC POLYHYDRIDE CLUSTER COMPLEXES OF IRIDIUM WITH CHELATING DIPHOSPHINE LIGANDS - X-RAY CRYSTAL AND MOLECULAR-STRUCTURES OF [IR2H5(PH2P(CH2)3PPH2)2]BF4 AND [IR3H7(PH2P(CH2)3PPH2)3](BF4)2 AND THEIR DYNAMIC NUCLEAR MAGNETIC-RESONANCE PROPERTIES [J].
WANG, HH ;
PIGNOLET, LH .
INORGANIC CHEMISTRY, 1980, 19 (06) :1470-1480
[47]   6-COORDINATE RUTHENIUM(II) COMPLEXES CONTAINING BOTH FORMATE AND ALKENYL LIGANDS - CRYSTAL-STRUCTURE OF RU(O2CH)(CO)(HC=CHPH)(PPH3)2 [J].
LOUMRHARI, H ;
MATAS, L ;
ROS, J ;
TORRES, MR ;
PERALES, A .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 403 (03) :373-381
[48]   METHYLENE CHAIN-LENGTH AND COORDINATION GEOMETRY IN TRIOSMIUM CLUSTERS CONTAINING DIPHOSPHINE LIGANDS - X-RAY CRYSTAL-STRUCTURES OF [OS-3(CO)(10)(MU-PH(2)P(CH2)(N)PPH(2))] (N=4 OR 5) AND [OS-3(CO)(8)(MU-PH(2)PCH(2)PPH(2))(2)] [J].
KABIR, SE ;
MIAH, A ;
NESA, L ;
UDDIN, K ;
HARDCASTLE, KI ;
ROSENBERG, E ;
DEEMING, AJ .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 492 (01) :41-51
[49]   pi-2-Methylallylpalladium(II) complexes containing a nine-membered chelate ring with an azine diphosphine ligand: Crystal structure of [(eta(3)-2-MeC(3)H(4))Pd{E,Z-PPh(2)CH(2)C(Bu(t))=N-N=C(Bu(t))CH(2)PPh(2)}]Cl [J].
Cermak, J ;
Perera, SD ;
Shaw, BL ;
ThorntonPett, M .
INORGANICA CHIMICA ACTA, 1996, 244 (01) :115-120
[50]   SYNTHESES AND CHARACTERIZATION OF DINUCLEAR GOLD(I) RING AND OPEN-RING COMPLEXES CONTAINING SATURATED AND UNSATURATED DITHIOL BRIDGING LIGANDS AND PHOSPHINE OR BIS(DIPHOSPHINE) DONOR LIGANDS - CRYSTAL-STRUCTURES OF [AU2(MU-S(CH2)3S)(MU-DPPM)],[AU2(MU-MNT)(PPH3)2], [AU2(MU-S2C6H4)(PPH3)2], AND [AU4(MU-S2C6H3CH3)2(PET3)2] [J].
DAVILA, RM ;
ELDUQUE, A ;
GRANT, T ;
STAPLES, RJ ;
FACKLER, JP .
INORGANIC CHEMISTRY, 1993, 32 (09) :1749-1755
12345