Novel dihydridoruthenium(II) complexes with chelating diphosphine ligands, RuH2(CO)(diphosphine)(PPh3) (diphosphine = dppe, dppp, dppb, and dppf)

被引：0

作者：

Kawano, H

Tanaka, R

Fujikawa, T

Hiraki, K ^{[1
]}

Onishi, M

机构：

[1] Nagasaki Univ, Fac Engn, Dept Appl Chem, Nagasaki 8528521, Japan

[2] Nagasaki Univ, Grad Sch Marine Sci & Engn, Nagasaki 8528521, Japan

来源：

CHEMISTRY LETTERS | 1999年 / 05期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ligand exchange of [RuH2(CO)(PPh3)(3)] with some diphosphine ligands affords a series of [RuH2(CO)(diphosphine)(PPh3)] (diphosphine = dppe, dppp, dppb, and dppf). The X-ray structure analysis of [RuH2(CO)(dppp)(PPh3)] reveals its distorted octahedral structure. The diphosphine ligand complexes react with styrene to generate ruthenium(0) species, which successively proceed with the intramolecular C-H addition to give the cyclometallated aryl(hydrido)ruthenium(II) species.

引用

页码：401 / 402

页数：2

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