Comparative study of strontium adsorption on dioctahedral and trioctahedral smectites

被引:26
作者
Galambos, M. [1 ]
Osacky, M. [2 ,3 ]
Rosskopfova, O. [1 ]
Krajnak, A. [1 ]
Rajec, P. [1 ]
机构
[1] Comenius Univ, Dept Nucl Chem, Fac Nat Sci, Bratislava 84215, Slovakia
[2] Univ Alberta, Dept Chem & Mat Engn, Edmonton, AB T6G 2V4, Canada
[3] Comenius Univ, Dept Geol Mineral Deposits, Fac Nat Sci, Bratislava 84215, Slovakia
关键词
Adsorption; Strontium; Bentonite Jelsovy potok/Lieskovec; Montmorillonite SAz-1/STx-1; Hectorite SHCa-1; Saponite SapCa-2; RockJock; Radioactive waste; Deep geological repository; SOCIETY SOURCE CLAYS; EXCHANGE CAPACITY MEASUREMENTS; BASE-LINE; RADIATION-STABILITY; LIESKOVEC DEPOSIT; SORPTION; BENTONITE; MINERALS; MONTMORILLONITE; TEMPERATURE;
D O I
10.1007/s10967-012-1752-8
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Slovak bentonites characterized by good rheological, mineralogical and chemical stability are considered as suitable sealing barriers for construction of Slovak deep geological repository for high-level radioactive waste and spent nuclear fuel. There is several Slovak bentonite deposits, bentonites of which have appropriate adsorption properties meeting the geotechnical requirements for this type of barriers. Study of adsorption properties of bentonites (mainly smectites) is an essential step for developing the migration model long-lived corrosion and activation products, and fission products of uranium. Nuclear wastes contain the most important nuclear fission products, beta-emitter Sr-90 with long half-life, biological half-life and high mobility. The present paper investigates and compares the strontium adsorption properties of bentonites of different mineral composition consisted mainly of dioctahedral and trioctahedral smectites.
引用
收藏
页码:889 / 897
页数:9
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