Synthesis and characterization of Fe3+ doped TiO2 nanoparticles and films and their performance for photocurrent response under UV illumination

Undoped TiO2 and Fe3+ doped (0.1, 0.3, 0.6 and 1 wt.%) TiO2 nanoparticles have been synthesized by the acid-catalyzed sol-gel method. Iron cations are introduced in the initial solution, before gelification, what promotes their lattice localization. The Fe3+ doped TiO2 films have been fabricated using a dip-coating technique. The effect of iron content on the crystalline structure, phase transformation and grain growth were determined by X-ray diffraction (XRD), Raman spectroscopy, UV-visible diffused reflectance spectroscopy (DRS) and Electron paramagnetic resonance (EPR) spectroscopy. It has demonstrated that all catalysts are composed of mixed-phase crystals of anatase and brookite with anatase as dominant phase. The crystallinity of the brookite and anatase phases decreased with increasing the iron content. The analysis of EPR result further confirms that Fe3+ ion are successfully doped in the TiO2 lattice by substituting Ti4+. It was demonstrated that Fe3+ ion in the TiO2 films plays a role as the intermediate for the efficient separation of photogenerated hole-electron pairs and increases the photocurrent response of the film under UV light irradiation. The maximum photocurrent is obtained on the Fe3+ doped TiO2 film with 0.1% Fe, which is 1.46 times that achieved on undoped TiO2 film. Crown Copyright (C) 2012 Published by Elsevier B. V. All rights reserved.