Investigation of the hydrogen evolution on Ni deposited titanium oxide nano tubes

被引：23

作者：

Sahin, E. Altunbas ^{[1
]}

Mert, B. Dogru ^{[1
]}

Doslu, S. Toprak ^{[1
]}

Kardas, G. ^{[1
]}

Yazici, B. ^{[1
]}

机构：

[1] Cukurova Univ, Sci & Letters Fac, Dept Chem, TR-01330 Adana, Turkey

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2012年 / 37卷 / 16期

关键词：

Hydrogen evolution; Nano tube formation; Anodizing; Scanning electron microscopy; Energy dispersive X-ray; ALKALINE-MEDIUM; OXIDATION; ELECTRODE; METHANOL; ARRAYS; WATER; ELECTROOXIDATION; FABRICATION; CATALYST; CATHODE;

D O I：

10.1016/j.ijhydene.2012.05.059

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Titanium oxide nano tubes (TiOx) were prepared by the electrochemical anodizing method from at different process time and different potential in 0.1 M HF solution. Their morphologies were determined with surface photographs and scanning electron microscopy (SEM) images. Ni nano particles were deposited in conductive TiOx nano tubes arrays via pulsed electrodeposition method. Their catalytic activity towards the hydrogen evolution reaction (HER) was assessed by recording cyclic voltammetry technique, cathodic current potential curves, hydrogen gas volumes and electrochemical impedance spectroscopy techniques. The highest HER activity thought the studied is observed on the TiOx((30))-Ni. Copyright (C) 2012, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：11625 / 11631

页数：7

共 29 条

[1] Preparation and characterization of Pt/TiO2 nanotubes catalyst for methanol electro-oxidation [J].

Abida, Bochra ;

Chirchi, Lotfi ;

Baranton, Steve ;

Napporn, Teko Wilhelmin ;

Kochkar, Hafedh ;

Leger, Jean-Michel ;

Ghorbel, Abdelhamid .

APPLIED CATALYSIS B-ENVIRONMENTAL, 2011, 106 (3-4) :609-615

[2] Formation of titania nanotubes with high photo-catalytic activity [J].

Adachi, M ;

Murata, Y ;

Harada, M ;

Yoshikawa, S .

CHEMISTRY LETTERS, 2000, (08) :942-943

[3] Photocatalytic TiO2 films and membranes for the development of efficient wastewater treatment and reuse systems [J].

Choi, Hyeok ;

Stathatos, Elias ;

Dionysiou, Dionysios D. .

DESALINATION, 2007, 202 (1-3) :199-206

[4] Analysis of the hydrogen electrode reaction mechanism in thin-layer cells 1 Theory [J].

Fernandez, Jose L. .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2010, 650 (01) :90-97

[5] Electrocatalytic oxidation of methanol on a nickel electrode modified by nickel dimethylglyoxime complex in alkaline medium [J].

Golikand, AN ;

Shahrokhian, S ;

Asgari, M ;

Maragheh, MG ;

Irannejad, L ;

Khanchi, A .

JOURNAL OF POWER SOURCES, 2005, 144 (01) :21-27

[6] Tungsten carbide microsphere as an electrode for cathodic hydrogen evolution from water [J].

Ham, Dong Jin ;

Ganesan, Raman ;

Lee, Jae Sung .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2008, 33 (23) :6865-6872

[7] Electrochemical impedance studies of modified Ni-P and Ni-Cu-P deposits in alkaline medium [J].

Hameed, R. M. Abdel ;

Fekry, A. M. .

ELECTROCHIMICA ACTA, 2010, 55 (20) :5922-5929

[8] Synthesis of Pd or Pt/titanate nanotube and its application to catalytic type hydrogen gas sensor [J].

Han, Chi-Hwan ;

Hong, Dae-Woong ;

Kim, Il-Jin ;

Gwak, Jihye ;

Han, Sang-Do ;

Singh, Krishan C. .

SENSORS AND ACTUATORS B-CHEMICAL, 2007, 128 (01) :320-325

[9] Electrocatalytic activation of Ni electrode for hydrogen production by electrodeposition of Co and V species [J].

Kaninski, Milica P. Marceta ;

Nikolic, Vladimir M. ;

Tasic, Gvozden S. ;

Rakocevic, Zlatko Lj. .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (02) :703-709

[10] Effect of some primary alcohols on hydrogen yield on platinum cathode in chloride solution [J].

Kardas, G ;

Yazici, B ;

Erbil, M .

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2003, 28 (11) :1213-1218

← 1 2 3 →