Phase diagram prediction of recycling aqueous two-phase systems formed by a light-sensitive copolymer and dextran

被引:1
作者
Shao, Zhihua [1 ]
Kong, Fanqi [1 ]
Cao, Xuejun [1 ]
机构
[1] E China Univ Sci & Technol, Dept Biochem Engn, State Key Lab Bioreactor Engn, Shanghai 200237, Peoples R China
关键词
Aqueous Two-phase Systems; Light-sensitive Polymer; Liquid-liquid Equilibria; Thermodynamic Models; EQUILIBRIUM; MODEL;
D O I
10.1007/s11814-009-0023-z
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Our Laboratory has synthesized a novel light-sensitive and recycling copolymer P,,,,. The P,, copolymer could form recycling aqueous two-phase systems with Dextran. Recycling aqueous two-phase systems have important application in bioseparation engineering. Phase diagram prediction of the novel aqueous two-phase systems also is an important aspect in engineering. This article applied the Cabezas model and effective excluded volume (EEV) model to the experimental data of light-sensitive recycling aqueous two-phase systems. It has been found that the EEV model could consist with experimental data very well. The maximum absolute error and average absolute error is 0.81% (wt%) and 0.23% (wt%), respectively.
引用
收藏
页码:147 / 152
页数:6
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