The influence of the electrodeposition potential on the morphology of Cu2O/TiO2 nanotube arrays and their visible-light-driven photocatalytic activity for hydrogen evolution

被引:54
作者
Zhang, Shengsen [1 ]
Peng, Biyu [1 ]
Yang, Siyuan [2 ]
Fang, Yueping [2 ]
Peng, Feng [1 ]
机构
[1] S China Univ Technol, Sch Chem & Chem Engn, Minist Educ, Key Lab Enhance Heat Transfer & Energy Conservat, Guangzhou 510640, Guangdong, Peoples R China
[2] South China Agr Univ, Coll Sci, Inst Biomat, Guangzhou 510642, Guangdong, Peoples R China
基金
中国国家自然科学基金; 中国博士后科学基金;
关键词
TiO2 nanotube arrays; Cu2O; Electrodeposition; Photoelectrochemical property; Hydrogen evolution; WATER; CU2O;
D O I
10.1016/j.ijhydene.2013.08.081
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The influence of the electrodeposition potential on the morphology of Cu2O/TiO2 nanotube arrays (Cu2O/TNA) and their visible-light-driven photocatalytic activity for hydrogen evolution have been investigated for the first time in this work. The photocatalytic hydrogen evolution rate of the as-prepared Cu2O/TNA at the deposition potential of -0.8 V was about 42.4 times that of the pure TNA under visible light irradiation. This work demonstrated a feasible and simple electrodeposition method to fabricate an effective and recyclable visible-light-driven photocatalyst for hydrogen evolution. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:13866 / 13871
页数:6
相关论文
共 17 条
[1]   ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].
FUJISHIMA, A ;
HONDA, K .
NATURE, 1972, 238 (5358) :37-+
[2]   Electrodeposition preparation of octahedral-Cu2O-loaded TiO2 nanotube arrays for visible light-driven photocatalysis [J].
Huang, L. ;
Zhang, S. ;
Peng, F. ;
Wang, H. ;
Yu, H. ;
Yang, J. ;
Zhang, S. ;
Zhao, H. .
SCRIPTA MATERIALIA, 2010, 63 (02) :159-161
[3]   Pt/N-codoped TiO2 nanotubes and its photocatalytic activity under visible light [J].
Huang, L. H. ;
Sun, C. ;
Liu, Y. L. .
APPLIED SURFACE SCIENCE, 2007, 253 (17) :7029-7035
[4]   "In situ" XPS study of band structures at Cu2O/TiO2 heterojunctions interface [J].
Huang, Lei ;
Peng, Feng ;
Ohuchi, Fumio S. .
SURFACE SCIENCE, 2009, 603 (17) :2825-2834
[5]  
Jin Z., 2012, J.Nanoeng. Nanomanuf, V2, P49
[6]   Review on Modified TiO2 Photocatalysis under UV/Visible Light: Selected Results and Related Mechanisms on Interfacial Charge Carrier Transfer Dynamics [J].
Kumar, S. Girish ;
Devi, L. Gomathi .
JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (46) :13211-13241
[7]   Highly Stabilized and Finely Dispersed Cu2O/TiO2: A Promising Visible Sensitive Photocatalyst for Continuous Production of Hydrogen from Glycerol:Water Mixtures [J].
Lalitha, Kannekanti ;
Sadanandam, Gullapelli ;
Kumari, Valluri Durga ;
Subrahmanyam, Machiraju ;
Sreedhar, Bojja ;
Hebalkar, Neha Y. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (50) :22181-22189
[8]   Facile preparation and size-dependent photocatalytic activity of Cu2O nanocrystals modified titania for hydrogen evolution [J].
Li, Likun ;
Xu, Leilei ;
Shi, Weidong ;
Guan, Jianguo .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (02) :816-822
[9]   Photocatalytic hydrogen production from aqueous methanol solutions under visible light over Na(BixTa1-x)O3 solid-solution [J].
Li, Zhonghua ;
Wang, Yanxin ;
Liu, Jiawen ;
Chen, Gang ;
Li, Yingxuan ;
Zhou, Chao .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2009, 34 (01) :147-152
[10]   Deposition of CdS nanoparticles within free-standing both-side-open stretched TiO2 nanotube-array films for the enhancement of photoelectrochemical performance [J].
Liou, Ya-Hsuan ;
Kao, Li-Cheng ;
Tsai, Meng-Che ;
Lin, Chin-Jung .
ELECTROCHEMISTRY COMMUNICATIONS, 2012, 15 (01) :66-69