Accelerated Ageing of Polypropylene Stabilized by Phenolic Antioxidants Under High Oxygen Pressure

Polypropylene (PP) samples stabilized by a hindered phenol (Irganox 1010) were submitted to thermal ageing at 80 degrees C in air at atmospheric pressure or in pure oxygen at 5.0 MPa pressure. Both the polymer oxidation and the stabilizer consumption were monitored by Infrared spectrometry and thermal analysis. The stabilizer efficiency, as assessed by the ratio induction time/stabilizer concentration is almost constant at atmospheric pressure even when the stabilizer concentration is higher than its solubility limit in PP (0.4% or 24 x 10(-3) mol L-1). In contrast, at high pressure, the efficiency decreases almost hyperbolically with the stabilizer concentration when this latter is higher than 6.0 x 10(-3) mol L-1. The results indicate the existence of a direct phenol-oxygen reaction negligible at low oxygen pressure but significant at 5.0 MPa pressure. The reality of this reaction has been proved on the basis of a study of the thermal oxidation of a phenol solution in a nonoxidizable solvent. A kinetic model of PP oxidation in which stabilization involves three reactions has been proposed. It simulates correctly the effect of oxygen pressure and stabilizer concentration on carbonyl build-up and stabilizer consumption. (C) 2008 Wiley Periodicals, Inc. J Appl Polyra Sci 110: 3313-3321, 2008