Highly efficient vinylaromatics generation via iron-catalyzed sp3 C-H bond functionalization CDC reaction: a novel approach to preparing substituted benzo[α]phenazines

被引：72

作者：

Lou, Shao-Jie ^{[1
]}

Xu, Dan-Qian ^{[1
]}

Shen, Dan-Feng ^{[1
]}

Wang, Yi-Feng ^{[1
]}

Liu, Yun-Kui ^{[1
]}

Xu, Zhen-Yuan ^{[1
]}

机构：

[1] Zhejiang Univ Technol, Catalyt Hydrogenat Res Ctr, State Key Lab Breeding Base Green Chem Synth Tech, Hangzhou 310014, Zhejiang, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 98期

关键词：

N-SULFONYL ALDIMINES; AMMONIUM IODIDE; CYANATION; OXIDATION; SCOPE; ALKYLATION; ACTIVATION; AZAARENES; ADJACENT; ARENES;

D O I：

10.1039/c2cc36708d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An iron-catalyzed benzylic vinylation was developed to transfer the carbon atom in the N,N-dimethyl moiety of N, N-dimethyl-acetamide (or N,N-dimethylformamide) to 2-methyl azaarenes to generate 2-vinyl azaarenes.

引用

页码：11993 / 11995

页数：3

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