Enantioselective Diels-Alder reaction of anthrone and maleimide catalyzed by a simple chiral tertiary amine

被引：19

作者：

Bai, Jian-Fei ^{[1
,2
]}

Guo, Yun-Long ^{[1
,2
]}

Peng, Lin ^{[1
]}

Jia, Li-Na ^{[1
,2
]}

Xu, Xiao-Ying ^{[1
]}

Wang, Li-Xin ^{[1
]}

机构：

[1] Chinese Acad Sci, Chengdu Inst Organ Chem, Key Lab Asymmetr Synth & Chirotechnol Sichuan Pro, Chengdu 610041, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 10039, Peoples R China

来源：

TETRAHEDRON | 2013年 / 69卷 / 03期

关键词：

Diels-Alder reactions; Anthrones; Maleimide; Chiral tertiary amine; ASYMMETRIC CYCLOADDITION; ANTHRACENE;

D O I：

10.1016/j.tet.2012.11.011

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Simple chiral tertiary amines with a special imide skeleton were first successfully applied to catalyze the enantioselective D A reaction of anthrone and maleimides in excellent yields (up to 96%) and enantioselectivities (up to 95% ee). (C) 2012 Elsevier Ltd. All rights reserved.

引用

页码：1229 / 1233

页数：5

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