A double intramolecular cage contraction within a self-assembled metallo-supramolecular bowl

被引：30

作者：

Brusilowskij, Boris ^{[1
]}

Neubacher, Saskia ^{[2
]}

Schalley, Christoph A. ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Chem & Biochem, D-14195 Berlin, Germany

[2] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 07期

关键词：

GAS-PHASE; PALLADIUM(II); RECOGNITION; COMPLEXES; CHEMISTRY; DESIGN;

D O I：

10.1039/b819412b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

When isolated in the high vacuum of an ESI-FTICR mass spectrometer, bowl-shaped metallo-supramolecular M6L4 assemblies undergo a surprising and mechanistically interesting intramolecular double cage contraction to yield smaller M3L2 cages.

引用

页码：785 / 787

页数：3

共 27 条

[1] Mass spectrometric studies of non-covalent compounds: why supramolecular chemistry in the gas phase? [J].

Baytekin, Bilge ;

Baytekin, H. Tarik ;

Schalley, Christoph A. .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2006, 4 (15) :2825-2841

[2]

Beves JE, 2006, DALTON T, P744, DOI 10.1039/b510860h

[3] Coordination number incommensurate cluster formation, part 21 -: Design, formation and properties of tetrahedral M4L4 and M4L6 supramolecular clusters [J].

Caulder, DL ;

Brückner, C ;

Powers, RE ;

König, S ;

Parac, TN ;

Leary, JA ;

Raymond, KN .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (37) :8923-8938

[4] Dynamic self-assembly of an M3L6 molecular triangle and an M4L8 tetrahedron from naked PdII ions and bis(3-pyridyl)-substituted arenes [J].

Chand, Dillip K. ;

Biradha, Kumar ;

Kawano, Masaki ;

Sakamoto, Shigeru ;

Yamaguchi, Kentaro ;

Fujita, Makoto .

CHEMISTRY-AN ASIAN JOURNAL, 2006, 1 (1-2) :82-90

[5] LIGAND SUBSTITUTION-REACTIONS OF SQUARE-PLANAR MOLECULES [J].

CROSS, RJ .

CHEMICAL SOCIETY REVIEWS, 1985, 14 (03) :197-223

[6] Reactivity of self-assembled supramolecular complexes in the gas phase: A supramolecular neighbor group effect [J].

Engeser, Marianne ;

Rang, Alexander ;

Ferrer, Montserrat ;

Gutierrez, Albert ;

Baytekin, H. Tarik ;

Schalley, Christoph A. .

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2006, 255 :185-194

[7] Spontaneous assembly of ten components into two interlocked, identical coordination cages [J].

Fujita, M ;

Fujita, N ;

Ogura, K ;

Yamaguchi, K .

NATURE, 1999, 400 (6739) :52-55

[8] GUEST-INDUCED ORGANIZATION OF A 3-DIMENSIONAL PALLADIUM(II) CAGE-LIKE COMPLEX - A PROTOTYPE FOR INDUCED-FIT MOLECULAR RECOGNITION [J].

FUJITA, M ;

NAGAO, S ;

OGURA, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (05) :1649-1650

[9] Coordination assemblies from a Pd(II)-cornered square complex [J].

Fujita, M ;

Tominaga, M ;

Hori, A ;

Therrien, B .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :369-378

[10]

Fujita M, 1998, ANGEW CHEM INT EDIT, V37, P2082, DOI 10.1002/(SICI)1521-3773(19980817)37:15<2082::AID-ANIE2082>3.0.CO

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