The new method for the synthesis of fullerols based on radical reaction

被引：3

作者：

Ratnikova, OV ^{[1
]}

Melenevskaya, EY ^{[1
]}

Amsharov, KY ^{[1
]}

Vlasova, EN ^{[1
]}

Volchek, BZ ^{[1
]}

Gribanov, AV ^{[1
]}

Shibaev, LA ^{[1
]}

Zgonnik, VN ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia

来源：

FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES | 2004年 / 12卷 / 1-2期

关键词：

fullerols; C-60 (OH)(x); C-60 (tert-BuO)(x); radical reaction; UV-irradiation;

D O I：

10.1081/FST-120027149

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The method for the synthesis of fullerols C-60(OH)(x) was developed, allowing to obtain products with low number of hydroxy groups attached to fullerene molecule. At the first stage, product C-60(tert-BuO)(x) was obtained by the radical reaction of C-60 with tert-butyl-peroxide under heating or UV-irradiation. At the second stage, fullerol C-60(OH)(x) was synthesized after the elimination of tert-butyl groups by acid treatment. Several samples C-60(OH), containing, different numbers (x = 2-5) of hydroxy groups were obtained. the main product had x = 2. The structure of the fullerols was confirmed by UV- and Fourier-transform infrared (FTIR)-spectroscopy and MALDI-TOF mass-spectrometry.

引用

页码：155 / 158

页数：4

共 5 条

[1] EFFICIENT SYNTHESIS OF POLYHYDROXYLATED FULLERENE DERIVATIVES VIA HYDROLYSIS OF POLYCYCLOSULFATED PRECURSORS [J].

CHIANG, LY ;

WANG, LY ;

SWIRCZEWSKI, JW ;

SOLED, S ;

CAMERON, S .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (14) :3960-3968

[2]

CHIANG LY, 2000, FULLERENES CHEM PHYS, P331

[3] C-60 FULLEROL FORMATION CATALYZED BY QUATERNARY AMMONIUM HYDROXIDES [J].

LI, J ;

TAKEUCHI, A ;

OZAWA, M ;

LI, XH ;

SAIGO, K ;

KITAZAWA, K .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (23) :1784-1785

[4] Infrared spectroscopy of all-carbon poly[60]fullerene polymer and [60]fullerene dimer model [J].

Ma, B ;

Milton, AM ;

Sun, YP .

CHEMICAL PHYSICS LETTERS, 1998, 288 (5-6) :854-860

[5]

Wilson S., 2000, FULLERENES CHEM PHYS, P437

← 1 →