Synthesis, isolation and characterization of cationic gold(I) N-heterocyclic carbene (NHC) complexes

被引：99
作者：
de Frémont, P
Stevens, ED
Fructos, MR
Díaz-Requejo, MM
Pérez, PJ
Nolan, SP [1 ]
机构：
[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA
[2] Univ Huelva, CSIC, Unidad Asoc,Dept Quim & Ciencia Mat, Lab Catalisis Homogenea, Huelva 21007, Spain
来源：
CHEMICAL COMMUNICATIONS | 2006年 / 19期
关键词：
D O I：
10.1039/b601547f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A number of cationic gold(I) complexes have been synthesized and found to be stabilized by the use of N-heterocyclic carbene ligands. These species are often employed as in situ-generated reactive intermediates in gold catalyzed organic transformations. An isolated, well-defined species was tested in gold-mediated carbene transfer reactions from ethyl diazoacetate.
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页码：2045 / 2047
页数：3
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