A novel preparation method of Sn-modified Pt nanoparticles and application for methanol oxidation

被引:18
作者
Du, Yongling [1 ]
Su, Biquan [1 ]
Zhang, Nuo [1 ]
Wang, Chunming [1 ]
机构
[1] Lanzhou Univ, Dept Chem, Lanzhou 730000, Peoples R China
基金
美国国家科学基金会;
关键词
Sn UPD; Pt nanoparticles; Methanol oxidation; Electrocatalytic; ITO electrode;
D O I
10.1016/j.apsusc.2008.07.147
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
With polystyrene latex spheres self-assembled on ITO glass as templates, highly ordered two-dimensional (2D) Pt nanoparticles (PtNPs) were prepared by electrochemical deposition. The morphology and element composition of PtNPs were characterized by scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The electrocatalytic properties of PtNPs/ITO and Sn underpotential deposition (UPD) modified PtNPs/ITO for methanol oxidation has been investigated by cyclic voltammetry (CV) and chronoamperometry (CA). The excellent electrocatalytic activity can be observed for these catalytic systems. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:2641 / 2645
页数:5
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