Cascade S(RN)1 reactions in 5-nitroimidazole series

被引：11

作者：

Vanelle, P ^{[1
]}

Benakli, K ^{[1
]}

Maldonado, J ^{[1
]}

Roubaud, C ^{[1
]}

Crozet, M ^{[1
]}

机构：

[1] FAC SCI & TECH ST JEROME,CNRS,LAB CHIM MOL ORGAN,F-13397 MARSEILLE 20,FRANCE

来源：

HETEROCYCLES | 1996年 / 43卷 / 04期

关键词：

D O I：

10.3987/COM-95-7309

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of 3-chloro-2-chloromethyl-1-(1-methyl-5-nitroimidazol-2-yl)prop-1-ene with 2-nitropropane anion which gives three products is shown to proceed by an initial S(RN)1 mechanism followed by another S(RN)1 leading to the bis-C-alkylation product or S(N)2 or S(N)2' and Michael reactions.

引用

页码：731 / 735

页数：5

共 14 条

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