Physical properties of two systems with induced antiferroelectric phase

被引:13
|
作者
Tykarska, Marzena [1 ]
Dabrowski, Roman [1 ]
Przedmojski, Jan [2 ]
Piecek, Wiktor [3 ]
Skrzypek, Katarzyna [1 ]
Donnio, Bertrand [4 ]
Guillon, Daniel [4 ]
机构
[1] Mil Univ Technol, Inst Chem, PL-00908 Warsaw, Poland
[2] Warsaw Univ Technol, Fac Phys, PL-00662 Warsaw, Poland
[3] Mil Univ Technol, Inst Phys, PL-00908 Warsaw, Poland
[4] IPCMS, GMO 23, F-67034 Strasbourg 2, France
关键词
antiferroelectric phase; phase induction; physical properties;
D O I
10.1080/02678290802364004
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two ferroelectric three-ring chiral esters, one with a partially fluorinated alkyl chain and another with a cyano terminal group, were mixed with a structurally similar compound having an alkyl terminal chain. In their mixtures an antiferroelectric phase was induced. The phase behaviour, spontaneous polarisation, tilt angle, smectic layer spacing and helical pitch of both systems were determined. The mechanism of the induction of an antiferroelectric phase is different in both cases, with highly tilted phases in former system and less tilted phases in the latter.
引用
收藏
页码:1053 / 1059
页数:7
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