Robust Bifunctional Lanthanide Cluster Based Metal-Organic Frameworks (MOFs) for Tandem Deacetalization-Knoevenagel Reaction

被引：173

作者：

Zhang, Yue ^{[1
]}

Wang, Yuxiang ^{[2
]}

Liu, Lin ^{[1
]}

Wei, Na ^{[1
]}

Gao, Ming-Liang ^{[1
]}

Zhao, Dan ^{[2
]}

Han, Zheng-Bo ^{[1
]}

机构：

[1] Liaoning Univ, Coll Chem, Shenyang 110036, Liaoning, Peoples R China

[2] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117585, Singapore

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 04期

基金：

中国国家自然科学基金;

关键词：

CARBON-DIOXIDE CAPTURE; HETEROGENEOUS CATALYSTS; CASCADE REACTIONS; CO2; POLYMERS; MIL-53; NET;

D O I：

10.1021/acs.inorgchem.7b03084

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of 12-connected lanthanide cluster based metal-organic frameworks (MOFs) have been constructed by [Ln(6)(mu(3)-OH)(8)(COO-)(12)] secondary building units (SBUs) and 2-aminobenzenedi-carboxylate (BDC-NH2) ligands. These obtained materials exhibit high chemical stability and generic thermal stability, especially in acidic and basic conditions. They also present commendable CO, adsorption capacity, and Yb-BDC-NH2 was further confirmed by a breakthrough experiment under both dry and wet conditions. Moreover, these materials possess both Lewis acid and Bronsted base sites that can catalyze one-pot tandem deacetalization-Knoevenagel condensation reactions.

引用

页码：2193 / 2198

页数：6

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