Identification of the Water Amidogen Radical Complex

被引：28

作者：

Ennis, Courtney P. ^{[2
]}

Lane, Joseph R. ^{[1
]}

Kjaergaard, Henrik G. ^{[1
]}

McKinley, Allan J. ^{[2
]}

机构：

[1] Univ Otago, Dept Chem, Dunedin, New Zealand

[2] Univ Western Australia, Sch Biomed Biomol & Chem Sci, Nedlands, WA 6009, Australia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 04期

关键词：

MATRIX-ISOLATION; ARGON MATRICES; H2O-CENTER-DOT-HO; DIMER;

D O I：

10.1021/ja808109m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The water amidogen radical complex (H2O-NH2) is a reactive intermediate in the atmospheric oxidation of ammonia by a hydroxyl radical. In the present study, we identify for the first time the H2O-NH2 complex using matrix isolation infrared spectroscopy. We corroborate our experimental findings with high level coupled cluster ab initio calculations.

引用

页码：1358 / +

页数：3

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