13C NMR spectroscopic study of scandium dimetallofullerene, Sc2@C84 vs. Sc2C2@ C82

被引:86
作者
Iiduka, Y
Wakahara, T
Nakajima, K
Tsuchiya, T
Nakahodo, T
Maeda, Y
Akasaka, T [1 ]
Mizorogi, N
Nagase, S
机构
[1] Univ Tsukuba, Ctr Tsukuba Adv Res Alliance, Tsukuba, Ibaraki 3058577, Japan
[2] Tokyo Gakugei Univ, Dept Chem, Tokyo 1848501, Japan
[3] Inst Mol Sci, Dept Theoret Mol Sci, Aichi 4448585, Japan
关键词
D O I
10.1039/b601738j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Although Sc2C84 has been widely believed to have the form Sc-2@C-84, the present C-13 NMR study reveals that it is a scandium carbide metallofullerene, Sc2C2@C-82, which has a C-82(C-3 nu) cage.
引用
收藏
页码:2057 / 2059
页数:3
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