Chiral porous metal-organic frameworks from chiral building units with different metrics

被引：7

作者：

Li, Qiaowei ^{[1
,2
]}

Shin, Sung Min ^{[3
]}

Moon, Dohyun ^{[4
]}

Jeong, Kyung Seok ^{[3
]}

Jeong, Nakcheol ^{[3
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

[2] Univ Calif Los Angeles, Dept Chem & Biochem, Ctr Reticular Chem, Los Angeles, CA 90095 USA

[3] Korea Univ, Dept Chem, Seoul 136701, South Korea

[4] Pohang Accelerator Lab POSTECH, Beamline Div, Pohang 790784, Kyung Buk, South Korea

来源：

CRYSTENGCOMM | 2013年 / 15卷 / 47期

基金：

中国国家自然科学基金;

关键词：

HYDROGEN STORAGE; MICROPOROSITY; INDUCTION; SORPTION; CRYSTAL; EXAMPLE; SOLIDS;

D O I：

10.1039/c3ce41586d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two chiral MOFs from the common Zn4O(COO)(6) SBUs and the congeners of chiral ligands were synthesized and characterized. The overall structures are differentiated by the ligand dimensions. These MOFs obtained from the flexible enantiopure struts exhibited severe chirality attenuation during the assembly.

引用

页码：10161 / 10164

页数：4

共 38 条

[1] Permanent microporosity and enantioselective sorption in a chiral open framework [J].

Bradshaw, D ;

Prior, TJ ;

Cussen, EJ ;

Claridge, JB ;

Rosseinsky, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (19) :6106-6114

[2] A metal-organic framework material that functions as an enantioselective catalyst for olefin epoxidation [J].

Cho, So-Hye ;

Ma, Baoqing ;

Nguyen, SonBinh T. ;

Hupp, Joseph T. ;

Albrecht-Schmitt, Thomas E. .

CHEMICAL COMMUNICATIONS, 2006, (24) :2563-2565

[3] Industrial applications of metal-organic frameworks [J].

Czaja, Alexander U. ;

Trukhan, Natalia ;

Mueller, Ulrich .

CHEMICAL SOCIETY REVIEWS, 2009, 38 (05) :1284-1293

[4] Homochiral Metal-Organic Frameworks for Heterogeneous Asymmetric Catalysis [J].

Dang, Dongbin ;

Wu, Pengyan ;

He, Cheng ;

Xie, Zhong ;

Duan, Chunying .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (41) :14321-14323

[5] Ordered porous materials for emerging applications [J].

Davis, ME .

NATURE, 2002, 417 (6891) :813-821

[6] Designed synthesis of 3D covalent organic frameworks [J].

El-Kaderi, Hani M. ;

Hunt, Joseph R. ;

Mendoza-Cortes, Jose L. ;

Cote, Adrien P. ;

Taylor, Robert E. ;

O'Keeffe, Michael ;

Yaghi, Omar M. .

SCIENCE, 2007, 316 (5822) :268-272

[7] Hybrid porous solids:: past, present, future [J].

Ferey, Gerard .

CHEMICAL SOCIETY REVIEWS, 2008, 37 (01) :191-214

[8] Review and Analysis of Molecular Simulations of Methane, Hydrogen, and Acetylene Storage in Metal-Organic Frameworks [J].

Getman, Rachel B. ;

Bae, Youn-Sang ;

Wilmer, Christopher E. ;

Snurr, Randall Q. .

CHEMICAL REVIEWS, 2012, 112 (02) :703-723

[9] Lanthanitin: A chiral nanoball encapsulating 18 lanthanum ions by ferritin-like assembly [J].

Jeong, Kyung Seok ;

Kim, Young Shin ;

Kim, Yrm Ju ;

Lee, Eunsung ;

Yoon, Ji Hye ;

Park, Won Hwa ;

Park, Young Woo ;

Jeon, Seung-Joon ;

Kim, Zee Hwan ;

Kim, Jaheon ;

Jeong, Nakcheol .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (48) :8134-8138

[10] A chiral trianglular coordination complex derived from (S,S)-1,2-dimethoxy-di-4-(2′-carboxyl-5′-pyridyl)phenyl ethane and Cu(II) by self-assembly [J].

Jeong, Kyung Seok ;

Kim, Sun Young ;

Oh, Youjin ;

Min, Dong Won ;

Kim, Jaheon ;

Jeong, Nakcheol .

CRYSTENGCOMM, 2007, 9 (04) :273-277

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