Thermochemical properties of 1-butyl-3-methylimidazolium nitrate

被引：67
|
作者：
Strechan, A. A. [1 ]
Kabo, A. G. [1 ]
Paulechka, Y. U. [1 ]
Blokhin, A. V. [1 ]
Kabo, G. J. [1 ]
Shaplov, A. S. [2 ]
Lozinskaya, E. I. [2 ]
机构：
[1] Belarusian State Univ, Fac Chem, Minsk 220030, BELARUS
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, INEOS, Moscow 119991, Russia
来源：
THERMOCHIMICA ACTA | 2008年 / 474卷 / 1-2期
关键词：
1-butyl-3-methylimidazolium; ionic liquid; heat capacity; bomb combustion calorimetty;
D O I：
10.1016/j.tca.2008.05.002
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Heat capacity for 1-butyl-3-methylimidazolium nitrate [C-4 mim][NO3] in the temperature range (5-370) K has been measured by adiabatic calorimetry. Temperatures and enthalpies of its phase transitions have been determined. Thermodynamic functions have been calculated for the crystalline and the liquid states. Phase transition temperatures for set of nitrate salts have been compared. Enthalpy of combustion and enthalpy of formation for crystalline [C-4 mim][NO3] have been determined using a static-bomb isoperibol combustion calorimeter. A correlation scheme for the estimation of C-p of ionic liquids has been developed. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：25 / 31
页数：7
相关论文
共 50 条
  • [1] Physical and electrochemical properties of 1-butyl-3-methylimidazolium bromide, 1-butyl-3-methylimidazolium iodide, and 1-butyl-3-methylimidazolium tetrafluoroborate
    Ki-Sub Kim
    Bae-Kun Shin
    Huen Lee
    Korean Journal of Chemical Engineering, 2004, 21 : 1010 - 1014
  • [2] Physical and electrochemical properties of 1-butyl-3-methylimidazolium bromide, 1-butyl-3-methylimidazolium iodide, and 1-butyl-3-methylimidazolium tetrafluoroborate
    Kim, KS
    Shin, BK
    Lee, H
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2004, 21 (05) : 1010 - 1014
  • [3] Confinement of 1-Butyl-3-methylimidazolium Nitrate in Metallic Silver
    Neouze, Marie-Alexandra
    Litschauer, Marco
    JOURNAL OF PHYSICAL CHEMISTRY B, 2008, 112 (51): : 16721 - 16725
  • [4] Structural and Conformational Analysis of 1-Butyl-3-methylimidazolium Nitrate
    Dean H. Johnston
    Mallory Gasbarre
    Carolanne E. Norris
    Journal of Chemical Crystallography, 2022, 52 : 140 - 151
  • [5] Structural and Conformational Analysis of 1-Butyl-3-methylimidazolium Nitrate
    Johnston, Dean H.
    Gasbarre, Mallory
    Norris, Carolanne E.
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2022, 52 (02) : 140 - 151
  • [6] Physicochemical properties of 1-butyl-3-methylimidazolium acetate
    Bogolitsyn, K. G.
    Skrebets, T. E.
    Makhova, T. A.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2009, 79 (01) : 125 - 128
  • [7] Physicochemical properties of 1-butyl-3-methylimidazolium acetate
    K. G. Bogolitsyn
    T. E. Skrebets
    T. A. Makhova
    Russian Journal of General Chemistry, 2009, 79 : 125 - 128
  • [8] Thermophysical and thermodynamic properties of 1-butyl-3-methylimidazolium tetrafluoroborate and 1-butyl-3-methylimidazolium hexafluorophosphate over an extended pressure range
    de Azevedo, RG
    Esperança, JMSS
    Najdanovic-Visak, V
    Visak, ZP
    Guedes, HJR
    da Ponte, MN
    Rebelo, LPN
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2005, 50 (03): : 997 - 1008
  • [9] On the properties of 1-butyl-3-methylimidazolium octylsulfate ionic liquid
    Davila, Maria J.
    Aparicio, Santiago
    Alcalde, Rafael
    Garcia, Begona
    Leal, Jose M.
    GREEN CHEMISTRY, 2007, 9 (03) : 221 - 232
  • [10] Refractive index and heat capacity of 1-butyl-3-methylimidazolium bromide and 1-butyl-3-methylimidazolium tetrafluoroborate, and vapor pressure of binary systems for 1-butyl-3-methylimidazolium bromide plus trifluoroethanol and 1-butyl-3-methylimidazolium tetrafluoroborate plus trifluoroethanol
    Kim, KS
    Shin, BK
    Lee, H
    Ziegler, F
    FLUID PHASE EQUILIBRIA, 2004, 218 (02) : 215 - 220
12345