Insertion of CO into a CH3-Pd bond in a heterodinuclear complex (dpe)MePd-Co(CO)(4). Preferential insertion of coordinated CO on a cobalt moiety

被引：32

作者：

Fukuoka, A

Fukagawa, S

Hirano, M

Komiya, S

机构：

[1] Department of Applied Chemistry, Faculty of Technology, Tokyo Univ. of Agric. and Technology, Koganei, Tokyo 184

来源：

CHEMISTRY LETTERS | 1997年 / 04期

关键词：

D O I：

10.1246/cl.1997.377

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A palladium-containing heterodinuclear complex (dpe)MePd-Co(CO)(4) shows higher reactivity toward CO insertion than PdMeCl(dpe) and (dpe)MePt-Co(CO)(4) to give an acetyl complex (dpe)AcPd-Co(CO)(4). The insertion of CO ligand in Co(CO)(4) is a kinetically favorable process.

引用

页码：377 / 378

页数：2

共 17 条

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