Synthesis of Pd-coated FeCo@Fe/C core-shell nanoparticles: microwave-induced 'top-down' nanostructuring and decoration

被引：14

作者：

Fashedemi, Omobosede O. ^{[1
]}

Julies, Basil ^{[2
]}

Ozoemena, Kenneth I. ^{[1
,3
]}

机构：

[1] Univ Pretoria, Dept Chem, ZA-0002 Pretoria, South Africa

[2] Univ Western Cape, Dept Phys, Cape Town, South Africa

[3] CSIR, ZA-0001 Pretoria, South Africa

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 20期

关键词：

OXYGEN; REDUCTION; CARBON; CATALYST;

D O I：

10.1039/c3cc38672d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a novel microwave-induced fast and efficient synthesis of sub-10 nm sized palladium-decorated FeCo@Fe core-shell nano-particles (ca. 3-7 nm) from a large-sized FeCo@Fe (0.21-1.5 mu m) precursor, suggesting 'top-down' nanosizing. The high electrochemical surface area, tolerance to methanol during oxygen reduction reaction, and the excellent stability of FeCo@Fe@Pd in alkaline electrolytes indicate that this nanomaterial may find future applications in Pd-based catalysis and/or alkaline fuel cells.

引用

页码：2034 / 2036

页数：3

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