Recent advances with calix[6]- and calix[8]arene organometallic catalysts

被引：8
|
作者：
Bonati, Federica Cester [1 ]
Secchi, Andrea [1 ]
Cera, Gianpiero [1 ]
机构：
[1] Univ Parma, Dipartimento Sci Chim Vita & Sostenibil Ambientale, Parco Area Sci 17-A, I-43124 Parma, Italy
来源：
TETRAHEDRON LETTERS | 2022年 / 112卷
关键词：
Calix[6]arenes; Calix[8]arenes; Catalysis; Metals; HYDROLYTIC KINETIC RESOLUTION; RING-OPENING POLYMERIZATION; GOLD CATALYSIS; REDUCTION; MOLYBDENUM; DINITROGEN; CALIXARENES; COMPLEXES; EFFICIENT; AMMONIA;
D O I：
10.1016/j.tetlet.2022.154221
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Calixarenes represent a fascinating class of macrocycles with several applications in supramolecular chemistry such as synthetic receptors for ion recognition, prototypes of molecular machines and devices and catalysts. In this scenario, larger calix[6]-and calix[8]arenes represent a modular platform to build novel and more efficient organometallic catalysts. Within this digest review, we aim to survey the latest advancements in this area of research including CAC and C-Het bond formations and fundamental inor-ganic transformations such as ammonia production and carbon dioxide reduction. (c) 2022 Elsevier Ltd. All rights reserved.
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页数：7
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