A high energy and power density hybrid supercapacitor based on an advanced carbon-coated Li4Ti5O12 electrode

被引:190
作者
Jung, Hun-Gi [2 ]
Venugopal, Nulu [2 ]
Scrosati, Bruno [1 ,2 ]
Sun, Yang-Kook [2 ,3 ]
机构
[1] Univ Roma La Sapienza, Dept Chem, I-00185 Rome, Italy
[2] Hanyang Univ, Dept WCU Energy Engn, Seoul 133791, South Korea
[3] Hanyang Univ, Dept Chem Engn, Seoul 133791, South Korea
基金
新加坡国家研究基金会;
关键词
Hybrid supercapacitor; Li4Ti5O12; Microsphere; High energy density; High power density; ACTIVATED CARBON; CELLS; BATTERIES; INTERCALATION; LIMN2O4; SPINEL; ANODE;
D O I
10.1016/j.jpowsour.2012.08.039
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We describe in this work the synthesis and the characterization of homogeneous, carbon-coated lithium titanium oxide micro spheres and demonstrate their use for the fabrication of an active negative electrode combined with a high surface area, activated carbon positive electrode to form an advanced non aqueous, hybrid supercapacitor. We show that this activated carbon/carbon coated-Li4Ti5O12 device retains 95% of its initial capacity after 1000 cycles with a maximum volumetric energy and power density of 57 Wh L-1 and 2600 W L-1, respectively. Due to this unique performance, the hybrid supercapacitor developed in this work is expected to be a very promising energy storage device suitable for applications that require high energy levels and fast charge and discharge cycles, such as those requested in the EV sector. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:266 / 271
页数:6
相关论文
共 50 条
[31]   Study of capacitive properties for LT-Li4Mn5O12 in hybrid supercapacitor [J].
Hao, Yan-Jing ;
Wang, Yan-Ying ;
Lai, Qiong-Yu ;
Zhao, Yan ;
Chen, Lian-Mei ;
Ji, Xiao-Yang .
JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2009, 13 (06) :905-912
[32]   Possibility of carbon coating with Li4Ti5O12 at low temperature for high rate of lithium ion batteries [J].
Hong, J. -E. ;
Oh, R. -G. ;
Yang, W. -G. ;
Ryu, K. -S. .
MATERIALS TECHNOLOGY, 2015, 30 (A1) :A18-A23
[33]   Is Li4Ti5O12 a solid-electrolyte-interphase-free electrode material in Li-ion batteries? Reactivity between the Li4Ti5O12 electrode and electrolyte [J].
Song, Min-Sang ;
Kim, Ryoung-Hee ;
Baek, Seung-Wook ;
Lee, Kug-Seung ;
Park, Kyusung ;
Benayad, Anass .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (03) :631-636
[34]   Carbon Coating with Oleic Acid on Li4Ti5O12 [J].
Gu, Fang ;
Chen, Gang .
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE, 2012, 7 (07) :6168-6179
[35]   Improved electrochemical performance of hybrid supercapacitor using Zr doped Li4Ti5O12 anode [J].
Choi, Hyeong-Jong ;
Lee, Seung-Hwan ;
Kim, Hong-Ki ;
Lee, Sung-Gap ;
Im, In-Ho ;
Lee, Young-Hie .
JOURNAL OF CERAMIC PROCESSING RESEARCH, 2016, 17 (03) :152-155
[36]   Electrochromic Behavior of Transparent Li4Ti5O12/FTO Electrode [J].
Yu, Xiqian ;
Wang, Rui ;
He, Yu ;
Hu, Yongsheng ;
Li, Hong ;
Huang, Xuejie .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2010, 13 (08) :J99-J101
[37]   Facile synthesis of N-doped carbon-coated Li4Ti5O12 microspheres using polydopamine as a carbon source for high rate lithium ion batteries [J].
Li, Hongsen ;
Shen, Laifa ;
Yin, Kuibo ;
Ji, Jing ;
Wang, Jie ;
Wang, Xiaoyan ;
Zhang, Xiaogang .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (24) :7270-7276
[38]   Evaluate Sulfone-Based Reduction Sensitive Electrolytes with Lithium Li4Ti5O12/Li and Symmetric Li4+XTi5O12/Li4Ti5O12 Cells [J].
Demeaux, J. ;
De Vito, E. ;
Le Digabel, M. ;
Galiano, H. ;
Lemordant, D. ;
Claude-Montigny, B. .
BATTERY ELECTROLYTES, 2013, 53 (36) :5-+
[39]   Templated spinel Li4Ti5O12 Li-ion battery electrodes combining high rates with high energy density [J].
Singh, Deepak P. ;
Mulder, Fokko M. ;
Wagemaker, Marnix .
ELECTROCHEMISTRY COMMUNICATIONS, 2013, 35 :124-127
[40]   Does Li4Ti5O12 need carbon in lithium ion batteries? Carbon-free electrode with exceptionally high electrode capacity [J].
Song, Min-Sang ;
Benayad, Anass ;
Choi, Young-Min ;
Park, Kyu-Sung .
CHEMICAL COMMUNICATIONS, 2012, 48 (04) :516-518