A high energy and power density hybrid supercapacitor based on an advanced carbon-coated Li4Ti5O12 electrode

被引:190
作者
Jung, Hun-Gi [2 ]
Venugopal, Nulu [2 ]
Scrosati, Bruno [1 ,2 ]
Sun, Yang-Kook [2 ,3 ]
机构
[1] Univ Roma La Sapienza, Dept Chem, I-00185 Rome, Italy
[2] Hanyang Univ, Dept WCU Energy Engn, Seoul 133791, South Korea
[3] Hanyang Univ, Dept Chem Engn, Seoul 133791, South Korea
基金
新加坡国家研究基金会;
关键词
Hybrid supercapacitor; Li4Ti5O12; Microsphere; High energy density; High power density; ACTIVATED CARBON; CELLS; BATTERIES; INTERCALATION; LIMN2O4; SPINEL; ANODE;
D O I
10.1016/j.jpowsour.2012.08.039
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We describe in this work the synthesis and the characterization of homogeneous, carbon-coated lithium titanium oxide micro spheres and demonstrate their use for the fabrication of an active negative electrode combined with a high surface area, activated carbon positive electrode to form an advanced non aqueous, hybrid supercapacitor. We show that this activated carbon/carbon coated-Li4Ti5O12 device retains 95% of its initial capacity after 1000 cycles with a maximum volumetric energy and power density of 57 Wh L-1 and 2600 W L-1, respectively. Due to this unique performance, the hybrid supercapacitor developed in this work is expected to be a very promising energy storage device suitable for applications that require high energy levels and fast charge and discharge cycles, such as those requested in the EV sector. Crown Copyright (C) 2012 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:266 / 271
页数:6
相关论文
共 50 条
[21]   Excellent performance of carbon-coated TiO2/Li4Ti5O12 composites with low Li/Ti ratio for Li-ion storage [J].
Yang, Wei ;
Bai, Xue ;
Li, Tao ;
Ma, Yuan-Yuan ;
Qi, Yong-Xin ;
Yin, Long-Wei ;
Li, Hui ;
Lun, Ning ;
Bai, Yu-Jun .
RSC ADVANCES, 2015, 5 (113) :93155-93161
[22]   High Tap Density Li4Ti5O12 Microspheres: Synthetic Conditions and Advanced Electrochemical Performance [J].
Ren, Jianxin ;
Ming, Hai ;
Jia, Zhenyong ;
Zhang, Yanqing ;
Ming, Jun ;
Zhou, Qun ;
Zheng, Junwei .
ENERGY TECHNOLOGY, 2017, 5 (09) :1680-1686
[23]   Carbon coating to suppress the reduction decomposition of electrolyte on the Li4Ti5O12 electrode [J].
He, Yan-Bing ;
Ning, Feng ;
Li, Baohua ;
Song, Quan-Sheng ;
Lv, Wei ;
Du, Hongda ;
Zhai, Dengyun ;
Su, Fangyuan ;
Yang, Quan-Hong ;
Kang, Feiyu .
JOURNAL OF POWER SOURCES, 2012, 202 :253-261
[24]   Characterization and electrochemical properties of carbon-coated Li4Ti5O12 prepared by a citric acid sol-gel method [J].
Wang, Jin ;
Liu, Xiao-Min ;
Yang, Hui ;
Shen, Xiao-dong .
JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (03) :712-718
[25]   Synthesis and electrochemical performance of spinel Li4Ti5O12 electrode material [J].
Ruan Yan-Li ;
Tang Zhi-Yuan ;
Peng Qing-Wen .
JOURNAL OF INORGANIC MATERIALS, 2006, 21 (04) :873-879
[26]   Nitrogen and sulfur co-doped carbon-coated Li4Ti5O12 composite to enhance lithium storage properties [J].
Kairui Tao ;
Shize Fu ;
Mingzhe Yang ;
Ning Zhang ;
Kun Liu ;
Wenlong Liu ;
Yuhao Zhou ;
Song Li ;
Juncai Sun .
Ionics, 2024, 30 :2083-2091
[27]   Improving rate capabilities of hybrid supercapacitor using Li4Ti5-xZrxO12/activated carbon [J].
Lee, Seung-Hwan ;
Jeoung, Tae-Hoon ;
Nam, Sung-Pill ;
Im, In-Ho .
JOURNAL OF CERAMIC PROCESSING RESEARCH, 2016, 17 (03) :139-143
[28]   Electrochemical behaviors of wax-coated Li powder/Li4Ti5O12 cells [J].
Park, Han Eol ;
Seong, Il Won ;
Yoon, Woo Young .
JOURNAL OF POWER SOURCES, 2009, 189 (01) :499-502
[29]   High performance hybrid supercapacitors using granule Li4Ti5O12/Carbon nanotube anode [J].
Lee, Byung-Gwan ;
Lee, Seung-Hwan ;
Ahn, Hyo-Jin ;
Yoon, Jung-Rag .
JOURNAL OF ALLOYS AND COMPOUNDS, 2018, 748 :882-888
[30]   Scalable in Situ Synthesis of Li4Ti5O12/Carbon Nanohybrid with Supersmall Li4Ti5O12 Nanoparticles Homogeneously Embedded in Carbon Matrix [J].
Zheng, Luyao ;
Wang, Xiaoyan ;
Xia, Yonggao ;
Xia, Senlin ;
Metwalli, Ezzeldin ;
Qiu, Bao ;
Ji, Qing ;
Yin, Shanshan ;
Xie, Shuang ;
Fang, Kai ;
Liang, Suzhe ;
Wang, Meimei ;
Zuo, Xiuxia ;
Xiao, Ying ;
Liu, Zhaoping ;
Zhu, Jin ;
Mueller-Buschbaum, Peter ;
Cheng, Ya-Jun .
ACS APPLIED MATERIALS & INTERFACES, 2018, 10 (03) :2591-2602