Chirality delivery through multiple and helical H-bonding from chiral coordination complex to its supramolecular architecture

被引：12

作者：

Zheng, Chun-Ying ^{[1
]}

Li, Hui ^{[1
]}

机构：

[1] Beijing Inst Technol, Sch Chem, Minist Educ, Key Lab Clusters Sci, Beijing 100081, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2013年 / 34卷

关键词：

Chirality delivery; Circular dichroism; Nucleotide complex; Supramolecular architecture; METAL-ORGANIC FRAMEWORKS; CIRCULAR-DICHROISM; GUANOSINE 5'-MONOPHOSPHATE; 5'-GUANOSINE MONOPHOSPHATE; NUCLEOSIDES; ABSORPTION; INDUCTION; ISOMERISM; BIPHENYL; SINGLE;

D O I：

10.1016/j.inoche.2013.04.038

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The path of the chirality delivery in the crystalline and chiral nucleotide-Co(II) complex, [Co(GMP)(H2O)(5)]center dot 3H(2)O (GMP = guanosine-5'-monophosphate), has been studied based on X-ray single crystal diffraction analysis, liquid- and solid-state circular dichroism (CD) spectroscopy. The multiple and helical H-bonding is a distinctive way of chirality delivery from the discrete molecules to three-dimensional supramolecular architecture. (c) 2013 The Authors. Published by Elsevier B.V. All rights reserved.

引用

页码：30 / 33

页数：4

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