Post-synthetic modification of conjugated microporous polymers

被引：110

作者：

Ratvijitvech, Thanchanok ^{[1
,2
]}

Dawson, Robert ^{[1
,2
]}

Laybourn, Andrea ^{[1
,2
]}

Khimyak, Yaroslav Z. ^{[3
]}

Adams, Dave J. ^{[1
,2
]}

Cooper, Andrew I. ^{[1
,2
]}

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England

[2] Univ Liverpool, Ctr Mat Discovery, Liverpool L69 7ZD, Merseyside, England

[3] Univ E Anglia, Sch Pharm, Norwich NR4 7TJ, Norfolk, England

来源：

POLYMER | 2014年 / 55卷 / 01期

基金：

英国工程与自然科学研究理事会;

关键词：

Microporous; Polymer synthesis; Conjugated polymer; HIGH-SURFACE-AREA; COVALENT ORGANIC FRAMEWORKS; POSTSYNTHETIC MODIFICATION; INTRINSIC MICROPOROSITY; CARBON-DIOXIDE; FUNCTIONALIZATION; NETWORKS; CHEMISTRY; MEMBRANES; STORAGE;

D O I：

10.1016/j.polymer.2013.06.004

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Control over the surface functionality and microporosity in conjugated microporous polymers (CMPs) has been achieved by the post-synthetic modification of amines into amides of with different alkyl chains, one of which was chiral. The surface areas, pore volumes, carbon dioxide uptakes and isosteric heat of adsorption for carbon dioxide can be rationally tuned. (C) 2013 Elsevier Ltd. All rights reserved.

引用

页码：321 / 325

页数：5

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