Enzymatic synthesis of polyesters in ionic liquids

被引：76
|
作者：
Uyama, H [1 ]
Takamoto, T [1 ]
Kobayashi, S [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Kyoto 6068501, Japan
来源：
POLYMER JOURNAL | 2002年 / 34卷 / 02期
关键词：
enzymatic polymerization; ionic liquids; lipase; polyester;
D O I：
10.1295/polymj.34.94
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Enzymatic synthesis of polyesters has been achieved in ionic liquids, 1-butyl-3-methylimidazolinium tetrafluoroborate (1) and butylmethylimidazolinium hexafluorophosphate (2). Candida antarctica lipase catalyzed the ring-opening polymerization of ε-caprolactone (3) or the polycondensation of diethyl esters (4) and glycols (5) in the ionic liquids. The polymerization of 3 proceeded efficiently in 1 to give the polymer with molecular weight of several thousands.
引用
收藏
页码：94 / 96
页数：3
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