Synthesis of silver promoted CuMnOx catalyst for ambient temperature oxidation of carbon monoxide

被引:44
作者
Dey, Subhashish [1 ]
Dhal, Ganesh Chandra [1 ]
Mohan, Devendra [1 ]
Prasad, Ram [2 ]
机构
[1] IIT BHU, Dept Civil Engn, Varanasi, Uttar Pradesh, India
[2] IIT BHU, Dept Chem Engn & Technol, Varanasi, Uttar Pradesh, India
来源
JOURNAL OF SCIENCE-ADVANCED MATERIALS AND DEVICES | 2019年 / 4卷 / 01期
关键词
Hopcalite (CuMnOx) catalyst; Silver; Carbon monoxide; Deposition-precipitation; Reactive calcination; MANGANESE OXIDE CATALYSTS; CO OXIDATION; REACTIVE CALCINATION; COPPER; ROUTE; PERFORMANCE; EMISSIONS; ABATEMENT; SOOT;
D O I
10.1016/j.jsamd.2019.01.008
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The present research shows that the addition of silver (Ag), by the deposition-precipitation method, to a mixed CuMnOx catalyst can improve the activity of carbon monoxide (CO) oxidation. The CuMnOx catalyst doped with 3 wt.% Ag shows a higher catalytic activity as compared to the 1, 2, 4 and 5 wt.% Ag doped samples. The loading of Ag could introduce new active sites into the CuMnOx catalyst and reduce its deactivation. The order of the optimal calcination strategies based on the performance of catalysts for CO oxidation is as follows: Reactive Calcination > Flowing air > Stagnant air. All the catalysts were characterized by XRD, FTIR, BET, XPS and SEM-EDX techniques. It was found that the high active surface area was one of the main factors for the high catalytic activity of the Ag-promoted CuMnOx catalyst. (C) 2019 The Authors. Publishing services by Elsevier B.V. on behalf of Vietnam National University, Hanoi.
引用
收藏
页码:47 / 56
页数:10
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