Versatile Post-functionalization of Polyoxometalate Platforms By Using An Unprecedented Range of Palladium-Catalyzed Coupling Reactions

被引：21
作者：
Lorion, Melanie M. [1 ]
Matt, Benjamin [1 ]
Alves, Sandra [1 ]
Proust, Anna [1 ]
Poli, Giovanni [1 ]
Oble, Julie [1 ]
Izzet, Guillaume [1 ]
机构：
[1] Univ Paris 06, Inst Parisien Chim Mol, CNRS, UMR 7201, F-75252 Paris 05, France
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2013年 / 19卷 / 38期
关键词：
cross-coupling; organic-inorganic hybrids; palladium; polyoxometalates; ALLYLIC ALKYLATION; HECK REACTION; DAWSON; KEGGIN; SURFACTANTS; MOLECULES; SURFACES; SEQUENCE; CLUSTERS; BROMIDES;
D O I：
10.1002/chem.201301694
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Handy POMs: Several palladium-catalyzed coupling reactions have been applied to polyoxometalate post-functionalization. The feasibility of each reaction with one model substrate was investigated and each set of synthetic conditions was optimized to obtain full conversions and high purity hybrid compounds (see scheme). Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：12607 / 12612
页数：6
相关论文
共 64 条
  • [1] Kinetic Data for the Transmetalation/Reductive Elimination in Palladium-Catalyzed Suzuki-Miyaura Reactions: Unexpected Triple Role of Hydroxide Ions Used as Base
    Amatore, Christian
    Jutand, Anny
    Le Duc, Gaetan
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (08) : 2492 - 2503
  • [2] [Anonymous], 2012, ANGEW CHEM
  • [3] [Anonymous], THE MIZOROKI HECK RE
  • [4] Organometallic-polyoxometalate hybrid compounds: Metallosalen compounds modified by Keggin type polyoxometalates
    Bar-Nahum, I
    Cohen, H
    Neumann, R
    [J]. INORGANIC CHEMISTRY, 2003, 42 (11) : 3677 - 3684
  • [5] Synthesis, characterization and catalytic activity of a Wilkinson's type metal-organic-polyoxometalate hybrid compound
    Bar-Nahum, I
    Neumann, R
    [J]. CHEMICAL COMMUNICATIONS, 2003, (21) : 2690 - 2691
  • [6] Highly efficient peptide bond formation to functionalized Wells-Dawson-type polyoxotungstates
    Bareyt, S
    Piligkos, S
    Hasenknopf, B
    Gouzerh, P
    Lacôte, E
    Thorimbert, S
    Malacria, M
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (29) : 3404 - 3406
  • [7] Bareyt S., 2003, ANGEW CHEM, V115, P3526
  • [8] The heck reaction as a sharpening stone of palladium catalysis
    Beletskaya, IP
    Cheprakov, AV
    [J]. CHEMICAL REVIEWS, 2000, 100 (08) : 3009 - 3066
  • [9] Polyoxometalate-Based N-Heterocyclic Carbene (NHC) Complexes for Palladium-Mediated C-C Coupling and Chloroaryl Dehalogenation Catalysis
    Berardi, Serena
    Carraro, Mauro
    Iglesias, Manuel
    Sartorel, Andrea
    Scorrano, Gianfranco
    Albrecht, Martin
    Bonchio, Marcella
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (35) : 10662 - 10666
  • [10] SELF-ASSEMBLED MONOLAYERS CONTAINING OMEGA-MERCAPTOALKYLBORONIC ACIDS ADSORBED ONTO GOLD FORM A HIGHLY CROSS-LINKED, THERMALLY STABLE BORATE GLASS-SURFACE
    CAREY, RI
    FOLKERS, JP
    WHITESIDES, GM
    [J]. LANGMUIR, 1994, 10 (07) : 2228 - 2234
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