Alternative polymer supports for organic chemistry

被引:2
作者
Bergbreiter, DE [1 ]
机构
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
关键词
soluble polymers; supports; LPOS; homogeneous catalysis;
D O I
10.1002/(SICI)1098-1128(199909)19:5<439::AID-MED9>3.0.CO;2-7
中图分类号
R914 [药物化学];
学科分类号
100701 ;
摘要
The use of polymers other than divinylbenzene crosslinked polystyrene as supports in organic chemistry is discussed. Insoluble polymer alternatives to DVB crosslinked polystyrene discussed include porous polyethylene supports, polymer-supported functional colloids, micron and submicron-sized particles and hollow spheres and one-dimensional supports. Soluble polymers including polyethylene, poly(alkene oxide)s, polyacrylamides, and fluorinated acrylates are discussed along with thermomorphic strategies where liquid-liquid separation of a biphasic systems is used as a way to effect polymer recovery in systems that are monophasic on heating. (C) John Wiley & Sons, Inc.
引用
收藏
页码:439 / 450
页数:12
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