Effect of various pulp properties on the solubility of cellulose in sodium hydroxide solutions

被引：25
|
作者：
Kihlman, Martin [1 ]
Aldaeus, Fredrik [2 ]
Chedid, Fadia [2 ]
Germgard, Ulf [1 ]
机构：
[1] Karlstad Univ, Dept Chem Engn, SE-65188 Karlstad, Sweden
[2] Innventia AB, SE-11486 Stockholm, Sweden
来源：
HOLZFORSCHUNG | 2012年 / 66卷 / 05期
关键词：
cellulose; dissolution; NaOH-based solvents; pulp characterization; AQUEOUS-SOLUTION; DISSOLUTION; TEMPERATURE; FIBERS; SYSTEM; WATER;
D O I：
10.1515/hf-2011-0220
中图分类号：
S7 [林业];
学科分类号：
0829 ; 0907 ;
摘要：
The dissolution of pulps with varying characteristic properties, for example cellulose chain length or content of hemicellulose, has been investigated in two alkaline solvent systems [sodium hydroxide (NaOH)/urea/thiourea (8:8:6.5 by wt.) and NaOH/zince oxide (ZnO) (9:0.5 by wt.)]. One standard paper pulp, two dissolving pulps and three pretreated pulps were selected for this study. The dissolution parameters in focus were the fiber dimensions, average degree of polymerization (DP), polydispersity, water retention value and content of hemicelluloses. The solubility was not influenced by the fiber dimensions. The only significant properties, according to variable importance plot, were DP and composition of the hemicelluloses. It was also established that mass transfer effects during the dissolution stage plays an important role in the dissolution of cellulose derived from pulp fibers.
引用
收藏
页码：601 / 606
页数：6
相关论文
共 50 条
  • [31] Sodium hydroxide supported cellulose for efficient removal of cationic dyes from aquatic solutions in batch and column modes: Adsorption characteristics and mechanism study
    Al-Yosofy, Amal A. S.
    El-Gharkawy, El-Sayed R.
    Akl, Magda A.
    EGYPTIAN JOURNAL OF CHEMISTRY, 2024, 67 (09): : 647 - 668
  • [32] Effect of methylimidazole on cellulose/ionic liquid solutions and regenerated material therefrom
    Olsson, Carina
    Hedlund, Artur
    Idstrom, Alexander
    Westman, Gunnar
    JOURNAL OF MATERIALS SCIENCE, 2014, 49 (09) : 3423 - 3433
  • [33] Effect of rheological properties of dissolved cellulose/microfibrillated cellulose blend suspensions on film forming
    Saarikoski, Eve
    Rissanen, Marja
    Seppala, Jukka
    CARBOHYDRATE POLYMERS, 2015, 119 : 62 - 70
  • [34] The Research on Dissolving Properties of Biodegradable Cellulose Pulp
    Qian, Cheng
    MANUFACTURING SCIENCE AND TECHNOLOGY, PTS 1-8, 2012, 383-390 : 3998 - 4002
  • [35] Cellulose gelation in aqueous hydroxide solutions by CO2(g): Fact and theory
    Naserifar, Shirin
    Karna, Nabin Kumar
    Kozlowski, Aleksandra Maria
    Bernin, Diana
    Hasani, Merima
    CARBOHYDRATE POLYMER TECHNOLOGIES AND APPLICATIONS, 2024, 7
  • [36] Solubility Model for Ferrous Iron Hydroxide, Hibbingite, Siderite, and Chukanovite in High Saline Solutions of Sodium Chloride, Sodium Sulfate, and Sodium Carbonate
    Kim, Sungtae
    Marrs, Cassandra
    Nemer, Martin
    Jang, Jay Je-Hun
    ACS EARTH AND SPACE CHEMISTRY, 2017, 1 (10): : 647 - 663
  • [37] Effect of pulp prehydrolysis conditions on dissolution and regenerated cellulose pore structure
    Antti Koistinen
    Josphat Phiri
    Kavindra Kumar Kesari
    Tapani Vuorinen
    Thaddeus Maloney
    Cellulose, 2023, 30 : 2827 - 2840
  • [38] A Review of Sodium Nitrite Solubility in Water and Physical Properties of the Saturated Solutions
    Reynolds, Jacob G.
    Britton, Michael D.
    Belsher, Jeremy D.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2021, 66 (08) : 2931 - 2941
  • [39] The role of urea in the solubility of cellulose in aqueous quaternary ammonium hydroxide
    Walters, Mikayla G.
    Mando, Albaraa D.
    Reichert, W. Matthew
    West, Christy W.
    West, Kevin N.
    Rabideau, Brooks D.
    RSC ADVANCES, 2020, 10 (10) : 5919 - 5929
  • [40] Room-temperature dissolution and chemical modification of cellulose in aqueous tetraethylammonium hydroxide–carbamide solutions
    Juho Antti Sirviö
    Juha P. Heiskanen
    Cellulose, 2020, 27 : 1933 - 1950
12345