Ether-Functionalized Trialkylimidazolium Ionic Liquids: Synthesis, Characterization, and Properties

被引：43
作者：
Jin, Yide [1 ]
Fang, Shaohua [1 ]
Chai, Ming [1 ]
Yang, Li [1 ]
Hirano, Shin-ichi [2 ]
机构：
[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Technol, Shanghai 200240, Peoples R China
[2] Shanghai Jiao Tong Univ, Hirano Inst Mat Innovat, Shanghai 200240, Peoples R China
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2012年 / 51卷 / 34期
基金：
中国国家自然科学基金;
关键词：
TEMPERATURE MOLTEN-SALTS; SENSITIZED SOLAR-CELLS; CLOUD POINT EXTRACTION; LITHIUM BATTERY ELECTROLYTE; ELECTROCHEMICAL PROPERTIES; PHYSICOCHEMICAL PROPERTIES; POTENTIAL ELECTROLYTES; CAPACITOR APPLICATIONS; MELTING-POINT; LOW-VISCOSITY;
D O I：
10.1021/ie300849u
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
A family of new ether-functionalized ILs based on trialkylimidazolium cations with one or two ether groups and TFSA(-) anion was synthesized and characterized. Their properties including melting point, thermal stability, viscosity, conductivity, and electrochemical windows were determined and compared to those of the trialkylimidazolium ILs without ether group. The relationship between the cations structure and IL physicochemical properties was systematically studied. Most of these ether-fiinctionalized ILs were liquids at room temperature, and the melting points of 21 ILs were lower than -60 degrees C. At room temperature, 26 ILs owned the viscosities lower than 100 mPa s, and the viscosities of IM(2o1)12TFSA and IM(2o2)12TFSA were 57.4 and 54.4 mPa s.
引用
收藏
页码：11011 / 11020
页数：10
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共 69 条
  • [1] Synthesis and characterization of two ionic liquids with emphasis on their chemical stability towards metallic lithium
    Bazito, Fernanda F. C.
    Kawano, Yoshio
    Torresi, Roberto M.
    [J]. ELECTROCHIMICA ACTA, 2007, 52 (23) : 6427 - 6437
  • [2] Ionic Liquids with the Bis(fluorosulfonyl) imide Anion: Electrochemical Properties and Applications in Battery Technology
    Best, A. S.
    Bhatt, A. I.
    Hollenkamp, A. F.
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (08) : A903 - A911
  • [3] VAN DER WAALS VOLUMES + RADII
    BONDI, A
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) : 441 - +
  • [4] Hydrophobic, highly conductive ambient-temperature molten salts
    Bonhote, P
    Dias, AP
    Papageorgiou, N
    Kalyanasundaram, K
    Gratzel, M
    [J]. INORGANIC CHEMISTRY, 1996, 35 (05) : 1168 - 1178
  • [5] Melting point and molecular symmetry
    Brown, RJC
    Brown, RFC
    [J]. JOURNAL OF CHEMICAL EDUCATION, 2000, 77 (06) : 724 - 731
  • [6] Task-specific ionic liquids
    Davis, JH
    [J]. CHEMISTRY LETTERS, 2004, 33 (09) : 1072 - 1077
  • [7] Ionic liquid (molten salt) phase organometallic catalysis
    Dupont, J
    de Souza, RF
    Suarez, PAZ
    [J]. CHEMICAL REVIEWS, 2002, 102 (10) : 3667 - 3691
  • [8] Functionalized imidazolium ionic liquids as electrolyte components of lithium batteries
    Egashira, Minato
    Todo, Hirotaka
    Yoshimoto, Nobuko
    Morita, Masayuki
    Yamaki, Jun-ichi
    [J]. JOURNAL OF POWER SOURCES, 2007, 174 (02) : 560 - 564
  • [9] Low-viscosity and low-melting point asymmetric trialkylsulfonium based ionic liquids as potential electrolytes
    Fang, Shaohua
    Yang, Li
    Wei, Chao
    Peng, Chengxin
    Tachibana, Kazuhiro
    Kamijima, Kouichi
    [J]. ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (11) : 2696 - 2702
  • [10] One ether-functionalized guanidinium ionic liquid as new electrolyte for lithium battery
    Fang, Shaohua
    Tang, Yufeng
    Tai, Xingyao
    Yang, Li
    Tachibana, Kazuhiro
    Kamijima, Kouichi
    [J]. JOURNAL OF POWER SOURCES, 2011, 196 (03) : 1433 - 1441
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