Tetrakis(acetonitrile)copper(I) hexafluorophosphate catalyzed coumarin synthesis via pechmann condensation under solvent-free condition

被引:11
作者
Soleimani, Ebrahim [1 ]
Khodaei, Mohammad Mehdi [1 ]
Batooie, Nasim [1 ]
Samadi, Saadi [1 ]
机构
[1] Razi Univ, Dept Chem, Kermanshah 67149, Iran
关键词
EFFICIENT CATALYST; HIGHLY EFFICIENT; ACID; DERIVATIVES; NITRATE; SILICA; CLAY;
D O I
10.1002/jhet.814
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Tetrakis(acetonitrile)copper(I) hexafluorophosphate (Cu(CH3CN)4PF6) is used as an efficient catalyst in the Pechmann condensation reaction of phenols with ethyl acetoacetate leading to the formation of coumarin derivatives in excellent yields under solvent free conditions at ambient temperature. The method is simple, solvent-free and gives excellent yields in a short reaction time. J. Heterocyclic Chem.,(2011).
引用
收藏
页码:409 / 412
页数:4
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