Tetrakis(bis(trimethylsilyl)amido)uranium(IV): Synthesis and Reactivity

被引：45

作者：

Lewis, Andrew J. ^{[1
]}

Williams, Ursula J. ^{[1
]}

Carroll, Patrick J. ^{[1
]}

Schelter, Eric J. ^{[1
]}

机构：

[1] Univ Penn, Dept Chem, P Roy & Diana T Vagelos Labs, Philadelphia, PA 19104 USA

来源：

INORGANIC CHEMISTRY | 2013年 / 52卷 / 13期

基金：

美国国家科学基金会;

关键词：

ELECTRONIC-STRUCTURE; URANIUM; COMPLEXES; CHEMISTRY; ARYLOXIDE; DERIVATIVES; REDUCTION; OXIDATION; POCKET; AMIDE;

D O I：

10.1021/ic401181j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of the sterically saturated uranium(IV) complex U[N(SiMe3)(2)](4) (1) is demonstrated from the one electron oxidation of U[N(SiMe3)(2)](3) with a variety of oxidants in THF. A high yielding synthesis of 1 directly from UI3(THF)(4) is provided

引用

页码：7326 / 7328

页数：3

共 36 条

[1] TRIS((HEXAMETHYLDISILYL)AMIDO)URANIUM(III) - PREPARATION AND COORDINATION CHEMISTRY [J].

ANDERSEN, RA .

INORGANIC CHEMISTRY, 1979, 18 (06) :1507-1509

[2]

Arnold PL, 2012, NAT CHEM, V4, P668, DOI [10.1038/NCHEM.1392, 10.1038/nchem.1392]

[3] Carbon monoxide coupling and functionalisation at a simple uranium coordination complex [J].

Arnold, Polly L. ;

Turner, Zoe R. ;

Bellabarba, Ronan M. ;

Tooze, Robert P. .

CHEMICAL SCIENCE, 2011, 2 (01) :77-79

[4] OXIDATION CHEMISTRY OF A URANIUM(III) ARYLOXIDE [J].

AVENS, LR ;

BARNHART, DM ;

BURNS, CJ ;

MCKEE, SD ;

SMITH, WH .

INORGANIC CHEMISTRY, 1994, 33 (19) :4245-4254

[5] The Bis Metallacyclic Anion [U(N{SiMe3}2)(CH2SiMe2N{SiMe3})2]- [J].

Benaud, Olivier ;

Berthet, Jean-Claude ;

Thuery, Pierre ;

Ephritikhine, Michel .

INORGANIC CHEMISTRY, 2010, 49 (17) :8117-8130

[6] EARLY ACTINIDE ALKOXIDE CHEMISTRY - SYNTHESIS, CHARACTERIZATION, AND MOLECULAR-STRUCTURES OF TH(IV) AND U(IV) ARYLOXIDE COMPLEXES [J].

BERG, JM ;

CLARK, DL ;

HUFFMAN, JC ;

MORRIS, DE ;

SATTELBERGER, AP ;

STREIB, WE ;

VANDERSLUYS, WG ;

WATKIN, JG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10811-10821

[7] URANIUM(VI) ORGANOIMIDO COMPLEXES [J].

BURNS, CJ ;

SMITH, WH ;

HUFFMAN, JC ;

SATTELBERGER, AP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (08) :3237-3239

[8] A trigonal bipyramidal uranyl amido complex:: Synthesis and structural characterization of [Na(THF)2] [UO2(N(SiMe3)2)3] [J].

Burns, CJ ;

Clark, DL ;

Donohoe, RJ ;

Duval, PB ;

Scott, BL ;

Tait, CD .

INORGANIC CHEMISTRY, 2000, 39 (24) :5464-5468

[9]

Burrows R.C., 1962, J APPL POLY SCI, V6, P465

[10] A linear, O-coordinated η1-CO2 bound to uranium [J].

Castro-Rodriguez, I ;

Nakai, H ;

Zakharov, LN ;

Rheingold, AL ;

Meyer, K .

SCIENCE, 2004, 305 (5691) :1757-1759

← 1 2 3 4 →