Solid-state conversion of a MOF to a metal-organo polymeric framework ( MOPF) via [2+2] cycloaddition reaction

被引：48

作者：

Park, In-Hyeok ^{[1
,2
]}

Chanthapally, Anjana ^{[3
]}

Lee, Hyeong-Hwan ^{[1
,2
]}

Quah, Hong Sheng ^{[3
]}

Lee, Shim Sung ^{[1
,2
]}

Vittal, Jagadese J. ^{[1
,2
,3
]}

机构：

[1] Gyeongsang Natl Univ, Dept Chem, Jinju 660701, South Korea

[2] Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 660701, South Korea

[3] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 28期

关键词：

TOPOCHEMICAL POLYMERIZATIONS; COORDINATION POLYMERS; DIOLEFIN CRYSTALS; PHOTOPOLYMERIZATION; DESIGN;

D O I：

10.1039/c4cc00228h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bpeb ligands aligned in a slip-stacked manner in a two-fold interpenetrated non-porous metal-organic framework (MOF) [Zn-2(bpeb)-( bdc)(fa)(2)] undergo [2+ 2] cycloaddition reaction in a single-crystal to single-crystal manner to a non-interpenetrated 3D structure with a new topology comprising an organic polymer ligand and a 2D coordination polymer.

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收藏

页码：3665 / 3667

页数：3

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