Solid-state conversion of a MOF to a metal-organo polymeric framework ( MOPF) via [2+2] cycloaddition reaction

被引：48
作者：
Park, In-Hyeok [1 ,2 ]
Chanthapally, Anjana [3 ]
Lee, Hyeong-Hwan [1 ,2 ]
Quah, Hong Sheng [3 ]
Lee, Shim Sung [1 ,2 ]
Vittal, Jagadese J. [1 ,2 ,3 ]
机构：
[1] Gyeongsang Natl Univ, Dept Chem, Jinju 660701, South Korea
[2] Gyeongsang Natl Univ, Res Inst Nat Sci, Jinju 660701, South Korea
[3] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 28期
关键词：
TOPOCHEMICAL POLYMERIZATIONS; COORDINATION POLYMERS; DIOLEFIN CRYSTALS; PHOTOPOLYMERIZATION; DESIGN;
D O I：
10.1039/c4cc00228h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The bpeb ligands aligned in a slip-stacked manner in a two-fold interpenetrated non-porous metal-organic framework (MOF) [Zn-2(bpeb)-( bdc)(fa)(2)] undergo [2+ 2] cycloaddition reaction in a single-crystal to single-crystal manner to a non-interpenetrated 3D structure with a new topology comprising an organic polymer ligand and a 2D coordination polymer.
引用
收藏
页码：3665 / 3667
页数：3
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