Esterification of aliphatic acids with olefin promoted by Bronsted acidic ionic liquids

被引：136

作者：

Gu, YL ^{[1
]}

Shi, F ^{[1
]}

Deng, YQ ^{[1
]}

机构：

[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Green Chem, Lanzhou 730000, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2004年 / 212卷 / 1-2期

基金：

中国国家自然科学基金;

关键词：

ionic liquid; esterification; acid catalysis; olefin;

D O I：

10.1016/j.molcata.2003.10.039

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Addition reactions of aliphatic acids with olefins to give corresponding esters have been investigated using SO3H-functionalized ionic liquids as dual catalyst-solvent. The isolation of the desired products could be achieved via simple decantation and ionic liquids could be reused continuously after dried in vacuum (5-12 mmHg) at ca. 80 degreesC. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：71 / 75

页数：5

共 19 条

[11] Addition of carboxylic acids to cyclic olefins catalyzed by strong acidic ion-exchange resins [J].

Heidekum, A ;

Harmer, MA ;

Hoelderich, WF .

JOURNAL OF CATALYSIS, 1999, 181 (02) :217-222

[12]

Herrmann W. A., 1997, [No title captured], Patent No. [US 5663451 US, 5663451]

[13]

Inoue K., 1993, US Patent, Patent No. [5,241,106, 5241106]

[14] Recent developments in the use of non-aqueous ionic liquids for two-phase catalysis [J].

Olivier, H .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1999, 146 (1-2) :285-289

[15] ACID-OLEFIN ESTERIFICATION - ROLE OF OLEFIN [J].

RAETHER, LO ;

GAMRATH, HR .

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1963, 2 (02) :133-&

[16]

SANO K, 1993, Patent No. 5189201

[17]

Wasserscheid P, 2000, ANGEW CHEM INT EDIT, V39, P3772, DOI 10.1002/1521-3773(20001103)39:21<3772::AID-ANIE3772>3.0.CO

[18]

2-5

[19] Room-temperature ionic liquids. Solvents for synthesis and catalysis [J].

Welton, T .

CHEMICAL REVIEWS, 1999, 99 (08) :2071-2083

← 1 2 →