Functionalization of graphene oxide with naphthalenediimide diamine for high-performance cathode materials of lithium-ion batteries

被引：25
作者：
Song, Yidan [1 ]
Gao, Yuanrui [2 ]
Rong, Hongren [1 ]
Wen, Hao [1 ]
Sha, Yanyong [1 ]
Zhang, Hanping [1 ]
Liu, Hong-Jiang [2 ]
Liu, Qi [1 ,3 ]
机构：
[1] Changzhou Univ, Jiangsu Key Lab Fine Petrochem Engn, Adv Catalysis & Green Mfg Collaborat Innovat Ctr, Sch Petrochem Engn, 1 Gehu Rd, Changzhou 213164, Jiangsu, Peoples R China
[2] Shanghai Univ, Coll Sci, Dept Chem, 99 Shangda Rd, Shanghai 200444, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China
来源：
SUSTAINABLE ENERGY & FUELS | 2018年 / 2卷 / 04期
基金：
中国国家自然科学基金;
关键词：
ORGANIC ELECTRODE MATERIALS; RECHARGEABLE LITHIUM; ELECTROCHEMICAL PERFORMANCE; FACILE SYNTHESIS; STORAGE; DERIVATIVES; NANOSHEETS; POLYMERS;
D O I：
10.1039/c7se00543a
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Through the covalent bonding between naphthalenediimide diamine (NDIDA) and graphene oxide (GO), we synthesize NDIDA-functionalized graphene oxide (NDIDA-GO). The as-synthesized NDIDA-GO is characterized by powder X-ray diffraction, Fourier transform infrared spectroscopy, thermogravimetric analysis, Raman spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy, and the Brunauer-Emmett-Teller surface area analysis. As a cathode material for lithium-ion batteries, within a voltage window of 4.5-1.5 V, NDIDA-GO exhibits a high specific capacity, good cyclic stability, and rate capability, keeping a specific capacity of 240 mA h g(-1) after 50 cycles at 50 mA g(-1). This work provides an effective route for the development of high-performance organic-based cathode materials for lithium-ion batteries.
引用
收藏
页码：803 / 810
页数：8
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