Iron(II) phthalocyanine (FePc) over carbon support for oxygen reduction reaction electrocatalysts operating in alkaline electrolyte

被引：35

作者：

de Oliveira, Maida Aysla Costa ^{[1
]}

Ficca, Valerio C. A. ^{[1
]}

Gokhale, Rohan ^{[2
]}

Santoro, Carlo ^{[2
,3
]}

Mecheri, Barbara ^{[1
]}

D'Epifanio, Alessandra ^{[1
]}

Licoccia, Silvia ^{[1
]}

Atanassov, Plamen ^{[2
,4
]}

机构：

[1] Univ Roma Tor Vergata, Dept Chem Sci & Technol, Via Ric Sci, I-00133 Rome, Italy

[2] Univ New Mexico, Ctr Microengn Mat CMEM, Dept Chem & Biol Engn, Albuquerque, NM 87131 USA

[3] Univ Manchester, Sch Chem Engn & Analyt Sci, Oxford Rd, Manchester M13 9PL, Lancs, England

[4] Univ Calif Irvine, Fuel Cells Res Ctr, Dept Chem & Biomol Engn, Irvine, CA 92697 USA

来源：

JOURNAL OF SOLID STATE ELECTROCHEMISTRY | 2021年 / 25卷 / 01期

关键词：

PGM-free catalyst; RRDE; Alkaline media; Morphology; REDUCED GRAPHENE OXIDE; N-C ELECTROCATALYSTS; O-2; REDUCTION; METAL PHTHALOCYANINES; NONPRECIOUS CATALYST; DOPED GRAPHENE; NITROGEN; PERFORMANCE; COMPOSITE; MECHANISM;

D O I：

10.1007/s10008-020-04537-x

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

In this work, we initially report a detailed advancement in the utilization of metal-N(4)chelate macrocycles in the oxygen reduction reaction (ORR). Then, iron(II) phthalocyanines supported on two different carbon-based supports specifically carbon nanotube and black pearl (carbon spheres) were synthesized and their activities toward ORR in alkaline media were studied. With the help of physical and surface characterization like Raman, BET, XRD, XPS, and electron microscopy analysis, the similarity in surface chemistry and surface area of the materials and the differences in the structure and morphology of the supports were established. This work also brings forth the effect of support properties on the electrocatalytic activity of the materials by a detailed electrochemical analysis using rotating disk electrode in oxygen saturated 0.1 M KOH. Comparison with existing literature on Fe-phthalocyanine supported on diverse carbon support is presented.

引用

页码：93 / 104

页数：12

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