Effect of iron on pozzolanic activity of kaolin

被引:22
作者
Ghorbel, Halima [1 ]
Samet, Basma [1 ]
机构
[1] Ecole Natl Ingn Sfax, Lab Chim Ind, Sfax 3038, Tunisia
关键词
Kaolin; Pozzolan; Iron; Hematite; Goethite; TUNISIAN CLAYS; CEMENT; METAKAOLIN;
D O I
10.1016/j.conbuildmat.2013.02.068
中图分类号
TU [建筑科学];
学科分类号
0813 ;
摘要
The effect of iron on the pozzolanic activity of kaolin is studied. For this, model kaolin is enriched by different iron contents. It has been proved that iron is deposited on kaolinitic sheets in the form of hematite (Fe2O3) or goethite (FeOOH). The clays thus obtained are treated thermally at 700 degrees C for 5 h. Thereafter, calcined clays are added to white cement in the proportions (20/80) to provide blended cements. It is proved that iron improves the pozzolanic activity of kaolin until an optimum content, beyond which, the pozzolanic activity decreases. The highest amounts of C-S-H and lowest CH content are detected, by XRD and DSC, in hydrated blended cement with optimum iron level. SEM observations and DSC analyses prove that iron is located in C-S-H and ettringite structures. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:185 / 191
页数:7
相关论文
共 15 条
[1]   Properties of Omani artificial pozzolana (sarooj) [J].
Al-Rawas, AA ;
Hago, AW ;
Corcoran, TC ;
Al-Ghafri, KM .
APPLIED CLAY SCIENCE, 1998, 13 (04) :275-292
[2]  
Ambroise J., 1992, P 4 INT C FLY ASH SF, V1, P731
[3]   EFFECTS OF IRON AND ALUMINUM-OXIDES ON THE COLLOIDAL AND SURFACE-PROPERTIES OF KAOLIN [J].
ARIAS, M ;
BARRAL, MT ;
DIAZFIERROS, F .
CLAYS AND CLAY MINERALS, 1995, 43 (04) :406-416
[4]   HIGH-TEMPERATURE REACTIONS OF CLAY MINERAL MIXTURES AND THEIR CERAMIC PROPERTIES .1. KAOLINITE-MICA-QUARTZ MIXTURES WITH 25 WEIGHT-PERCENT QUARTZ [J].
BRINDLEY, GW ;
UDAGAWA, S .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1960, 43 (02) :59-65
[5]   Study on the potential use of Tunisian clays as pozzolanic material [J].
Chakchouk, A. ;
Samet, B. ;
Mnif, T. .
APPLIED CLAY SCIENCE, 2006, 33 (02) :79-88
[6]   Difference in pozzolanic behaviour of Tunisian clays with lime and cement [J].
Chakchouk, Ahlem ;
Samet, Basma ;
Bouaziz, Samir .
ADVANCES IN CEMENT RESEARCH, 2012, 24 (01) :11-22
[7]   The origin of the pozzolanic activity of calcined clay minerals: A comparison between kaolinite, illite and montmorillonite [J].
Fernandez, Rodrigo ;
Martirena, Fernando ;
Scrivener, Karen L. .
CEMENT AND CONCRETE RESEARCH, 2011, 41 (01) :113-122
[8]   POZZOLANIC REACTIONS OF 6 PRINCIPAL CLAY-MINERALS - ACTIVATION, REACTIVITY ASSESSMENTS AND TECHNOLOGICAL EFFECTS [J].
HE, CL ;
OSBAECK, B ;
MAKOVICKY, E .
CEMENT AND CONCRETE RESEARCH, 1995, 25 (08) :1691-1702
[9]   Thermal treatment of kaolin: the effect of mineralogy on the pozzolanic activity [J].
Kakali, G ;
Perraki, T ;
Tsivilis, S ;
Badogiannis, E .
APPLIED CLAY SCIENCE, 2001, 20 (1-2) :73-80
[10]   Influence of metakaolin as supplementary cementing material on strength and durability of concretes [J].
Ramezanianpour, A. A. ;
Jovein, H. Bahrami .
CONSTRUCTION AND BUILDING MATERIALS, 2012, 30 :470-479