Mechanosynthesis of nitrosobenzenes: a proof-of-principle study in combining solvent-free synthesis with solvent-free separations

被引：42

作者：

Huskic, Igor ^{[1
]}

Halasz, Ivan ^{[1
]}

Friscic, Tomislav ^{[2
]}

Vancik, Hrvoj ^{[1
]}

机构：

[1] Univ Zagreb, Fac Sci, Dept Chem, HR-10002 Zagreb, Croatia

[2] McGill Univ, Dept Chem, Montreal, PQ H3A 0B8, Canada

来源：

GREEN CHEMISTRY | 2012年 / 14卷 / 06期

关键词：

ONE-POT SYNTHESIS; SOLID-STATE; BALL-MILL; ORGANIC-SYNTHESIS; EFFICIENT; MECHANOCHEMISTRY; PERMANGANATE; CONVERSION; OXIDATION; NITRONES;

D O I：

10.1039/c2gc35410a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mechanochemical Oxone oxidation of selected para-substituted anilines was used as a rapid and solvent-free route to nitrosobenzenes; besides avoiding bulk solvents and short reaction times, this method exploits high vapour pressures of nitrosobenzenes for the solvent-free separation of the product by sublimation, demonstrating an entirely solvent-free route to chemical synthesis and product isolation.

引用

收藏

页码：1597 / 1600

页数：4

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