Potentiometric Study of Coated Graphite Electrode and Polymeric Membrane Electrode for the Determination of Sm3+Ion

被引：7

作者：

Upadhyay, Anjali ^{[1
]}

Singh, A. K. ^{[1
]}

Jain, A. K. ^{[1
]}

Gupta, Vinod Kumar ^{[1
]}

Bandi, Koteswara Rao ^{[1
]}

机构：

[1] Indian Inst Technol Roorkee, Dept Chem, Roorkee 247667, Uttar Pradesh, India

来源：

ELECTROANALYSIS | 2012年 / 24卷 / 07期

关键词：

Polymeric membrane electrodes; Coated graphite electrodes; Potentiometric electrodess; Ion selective electrodes; ION-SELECTIVE ELECTRODES; SCHIFF-BASES; PVC MEMBRANE; URANYL IONS; SENSOR; SAMARIUM(III); DIBENZO-24-CROWN-8; BORATOPHOSPHATE; FABRICATION; IONOPHORES;

D O I：

10.1002/elan.201200050

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Preliminary studies on the two Schiff bases N2-((3H-indol-3-yl)methylene)-6-phenyl-1,3,5-triazine-2,4-diamine (L1) and N2,N4-bis((3H-indol-3-yl)methylene)-6-phenyl-1,3,5-triazine-2,4-diamine (L2) have shown that they can act as Sm3+ selective electrodes. The performances of a polymeric membrane electrode and a coated graphite electrode based on L2 were compared and the CGE proved to be better, as it shows a low detection limit of 1.8x10-8 mol?L-1, a Nernstian slope of 19.6 +/- 0.4 mV decade-1 of activity with a response time of 11 s in the pH range of 3.09.0. The CGE was used to determine Sm3+ in medicinal plants and soil samples. It was also used to determine fluoride ions in mouthwash samples and in toothpaste.

引用

页码：1630 / 1638

页数：9

共 54 条

[1] LIPOPHILIC SALTS AS MEMBRANE ADDITIVES AND THEIR INFLUENCE ON THE PROPERTIES OF MACROELECTRODES AND MICROELECTRODES BASED ON NEUTRAL CARRIERS
AMMANN, D
PRETSCH, E
SIMON, W
LINDNER, E
BEZEGH, A
PUNGOR, E
[J]. ANALYTICA CHIMICA ACTA, 1985, 171 (MAY) : 119 - 129
[2] Selectivity of potentiometric ion sensors
Bakker, E
Pretsch, E
Bühlmann, P
[J]. ANALYTICAL CHEMISTRY, 2000, 72 (06) : 1127 - 1133
[3] RECOMMENDED PROCEDURES FOR CALIBRATION OF ION-SELECTIVE ELECTRODES
BUCK, RP
COSOFRET, VV
[J]. PURE AND APPLIED CHEMISTRY, 1993, 65 (08) : 1849 - 1858
[4] Antibacterial and antifugal mono- and di-substituted symmetrical and unsymmetrical triazine-derived Schiff-bases and their transition metal complexes
Chohan, ZH
Pervez, H
Rauf, A
Khan, KM
Maharvi, GM
Supuran, CT
[J]. JOURNAL OF ENZYME INHIBITION AND MEDICINAL CHEMISTRY, 2004, 19 (02) : 161 - 168
[5] Samarium(III)-selective electrode using neutral bis(thiaalkylxanthato)alkanes
Chowdhury, DA
Ogata, T
Kamata, S
Ohashi, K
[J]. ANALYTICAL CHEMISTRY, 1996, 68 (02) : 366 - 370
[6] Pre-concentration of rare earths using silica gel loaded with 1-(2-pyridylazo)-2-naphthol (PAN) and determination by energy dispersive X-ray fluorescence
Cornejo-Ponce, L
Peralta-Zamora, P
Bueno, MIMS
[J]. TALANTA, 1998, 46 (06) : 1371 - 1378
[7] PVC MATRIX MEMBRANE ION-SELECTIVE ELECTRODES - CONSTRUCTION AND LABORATORY EXPERIMENTS
CRAGGS, A
MOODY, GJ
THOMAS, JDR
[J]. JOURNAL OF CHEMICAL EDUCATION, 1974, 51 (08) : 541 - 544
[8] Simultaneous determination of neodymium and samarium in silicate rocks and minerals by isotope dilution inductively coupled plasma mass spectrometry: Results on twenty geochemical reference samples
D'Orazio, M
Tonarini, S
[J]. ANALYTICA CHIMICA ACTA, 1997, 351 (1-3) : 325 - 335
[9] PLASTICIZERS FOR LIQUID POLYMERIC MEMBRANES OF ION-SELECTIVE CHEMICAL SENSORS
EUGSTER, R
ROSATZIN, T
RUSTERHOLZ, B
AEBERSOLD, B
PEDRAZZA, U
RUEGG, D
SCHMID, A
SPICHIGER, UE
SIMON, W
[J]. ANALYTICA CHIMICA ACTA, 1994, 289 (01) : 1 - 13
[10] Determination of lanthanides (La, Ce, Nd, Sm) and other elements in metallic gallium by instrumental neutron activation analysis
Figueiredo, AMG
Avristcher, W
Masini, EA
Diniz, SC
Abrao, A
[J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2002, 344 (1-2) : 36 - 39

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