Structural Elucidation of the Illustrious Tebbe Reagent

被引：32
|
作者：
Thompson, Rick [1 ,2 ]
Nakamaru-Ogiso, Eiko [3 ]
Chen, Chun-Hsing [1 ,2 ]
Pink, Maren [1 ,2 ]
Mindiola, Daniel J. [1 ,2 ]
机构：
[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA
[2] Indiana Univ, Ctr Mol Struct, Bloomington, IN 47405 USA
[3] Univ Penn, Dept Biochem & Biophys, Perelman Sch Med, Philadelphia, PA 19104 USA
来源：
ORGANOMETALLICS | 2014年 / 33卷 / 01期
基金：
美国国家科学基金会;
关键词：
OLEFIN-METATHESIS; TITANIUM; REACTIVITY; COMPLEXES; ELECTRON;
D O I：
10.1021/om401108b
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The Tebbe reagent, [Cp2Ti(mu(2)-Cl)(mu(2)-CH2)AlMe2] (1), has finally been structurally characterized due to the fortuitous formation of cocrystals of 1 and [Cp2Ti(mu(2)-Cl)(2)AlMe2] (2). Single crystals of 1 and 2, despite being extremely reactive and forming an amorphous white coat, can be mounted and data collected to high resolution, thereby providing for the first time a solid-state representation of a titanium methylidene adduct with diphilic AlClMe2.
引用
收藏
页码：429 / 432
页数：4
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