Palladium-Catalyzed Cascade Oxidation/sp2 C-H Acylation of Azoarenes with Aryl Methanes

被引：99
作者：
Xiong, Feng [1 ]
Qian, Cheng [2 ]
Lin, Dongen [2 ]
Zeng, Wei [2 ]
Lu, Xiaoxia [1 ]
机构：
[1] Chinese Acad Sci, Chengdu Inst Biol, Chengdu 610041, Peoples R China
[2] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510641, Peoples R China
来源：
ORGANIC LETTERS | 2013年 / 15卷 / 21期
关键词：
BOND ACTIVATION; DIRECTING GROUP; OLEFINATION; ALKENYLATION; ACETANILIDES; DERIVATIVES; COMPLEXES; ACCESS; 2H-INDAZOLES; AZOBENZENE;
D O I：
10.1021/ol402537t
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A Pd-catalyzed cascade oxidation/sp(2) C-H bond acylation of azoarenes was developed in which readily available aryl methanes were used as the in situ generated acyl sources. This reaction provides a convenient access to ortho-acyl azoarenes under mild conditions.
引用
收藏
页码：5444 / 5447
页数：4
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